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‎"RUTHERFORD, ERNEST - NIELS BOHR - C.G. DARWIN. - THE DISCOVERY OF THE 'PROTON'.‎

‎The Structure of the Atom. (Rutherford) + (Darwin:) Collision of 'alpha' Particles with Light Atoms. + (Bohr:) On the Effect of Electric and Magnetic Fields on Spectral Lines‎

‎London, 1914. No wrappers, but stiched. All three papers contained in: ""Philosophical Magazine"", Sixth Series, Vol. 27. No. 159. March 1914. The whole issue issue offered (=no. 159): pp. 397-540 and 2 plates.Rutherford's paper.pp. 488-498. - Darwin's paper: pp. 499-506. - Bohr's paper: pp. 506-523. All clean and fine.‎

‎First edition and first printing of all three papers. Rutherford, in this paper for the first time identifies the hydrogen nucleus, and called it the 'positive electron'. He later called it 'the proton' . In his definitive paper of 1911 he estimated the radius of the nucleus, a hundred thousand times smaller than that of an atom. Darwin in his paper (offered here) gave a more precise measure.In the first lines of the paper Rutherford outlines the content ""The present paper and and the accompanying paper by Mr. C. Darwin (the second paper offered here) deal with certain points in connection with the ""nucleus"" theory of the atom which were purposely omitted in my first communication on that subject (Phil. Mag. May 1911). A brief account is given of the later investigations which have been made to test the theory and of the deductions which can be drawn from them. At the same time a brief statement is given of recent observations on the passage of alpha particles through hydrogen, which throw importent light on the dimensions of the nucleus."" - Rutherford had studies alpha-particles intensely in the years before 1914 and proved quite conclusively that the individual particle was a helium atom with its electrons removed. The alpha particles were like the positive rays that had been discovered by Goldstein (1886), and now in 1914 (the paper offered) Rutherford suggested that the simplest positive rays must be those obtained from the hydrogen and that these must be the fundamentall positively-charged particle. He names it a 'positive electron'.Darwin, in the paper offered ""concluded from the known data:""No force proportional to some power of the distance other than the inverse square can give the dependence (the Rutherford scattering cross section) on (the initial velocity)"", and he then calculated the distance of closest alpha-particle-nucleus approach.The paper by Niels Bohr relates to ""The Stark effect"". In 1913 appeared ""an importent new discovery: when atomic hydrogen is exposed to a static electrical field its spectral lines split, the amount of splitting being proportional to thefield strenght (the linear Stark effect). After Rutherford read this news in ""Nature"", he at once wrote to Bohr:'I think it is rather up to you at the present time to write something on....electric effects.'"" (A. Pais). Bohrs paper on The Stark effect appeared in 1914, the paper offered here. - Rosenfeld. Niels Bohr' publications No. 10).‎

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‎"LEIBNIZ (LEIBNITZ), G.F. - CHRISTIAAN HUYGENS - JOHANN BERNOULLI - JACOB BERNOULLI ET AL. - THE DISCOVERY OF THE ""CATENARY CURVE"" , THE ""LOGARITHMIC CURVE"" AND THE ""POLAR COORDINATES"".‎

‎1. De Linea in quam Flexile se pondere proprio curvat, ejeuque usu insignia adinveniendi quotcunque medias proportionales & Logarithmos. - 2. De Solutionibus Problematis Catenarii vel Funicularis in Actis A. 1691, aliisque a Dn. I.B. propositis. (1-2:...‎

‎Leipzig, Grosse & Gleditsch, 1691. 4to. Contemp. full vellum. Faint handwritten title on spine. a small stamp on titlepage. In: ""Acta Eruditorum Anno MDCLXXXXI"". (8),590,(6) pp. and 13 (of 15) folded engraved plates. The 2 first plates lacks, but they do not belong to the papers listed.Leibniz' papers: pp.277-281 a. 1 plate, pp. 435-439. Johann Bernoulli: pp. 274-276 a. 1 plate. Huygens: pp. 281-282. - Jacob Bernoulli: pp. 282-290 a. 1 plate.‎

‎All papers first apperance. All 5 of extreme importence in the development of the Calculus. Leibniz' 2 papers on the catenary curve (paper 1-2 offered here) was written at the instigation of Jacques Bernoulli. Following the example of Blaise Pascal, who had initiated, in 1658, a contest for the construction of the cycloid, Leibniz also provoked the geometers of his time, by challenging them to submit, at the fixed date of mid-1691, their geometric method for the construction of the catenary curve. Leibniz later provided the answer, followed by Johann Bernoulli and Huygens.'These two papers are a historical account of the origin of the study of this transcendental curve, and, at the same time, the first physical-geometric construction showing the species-relationship between the catenary and the logarithmic curves, as two companion curves" one arithmetic, the other geometric. All of the differentials of the catenary curve, are arithmetic means of corresponding differentials of the logarithmic curve" and, all of the differentials of the logarithmic curve, are geometric means of the catenary.'""The Catenary is the form of a hanging fully flexible rope or chain (the name comes from ""catena"", which means 'chain'), suspended on two points. The interest in this curve originated with Galileo, who thought that is was a parabola. Young Christiaan Huygens proved in 1646 that this cannot be the case. What the actual form was remained an open question till 1691, when Leibniz, Johann Bernoulli and the then much older Huygens sent solutions to the problem to the ""Acta"" (Jakob Bernoulli, 1690, Johann Bernoulli 1691, Huygens 1691 and Leibniz 1691), - these 4 1691-papers offered here - in which the previous year Jakob Bernoulli had challenged mathematicians to solve it. As published, the solutions did not reveal the methods, but through later publications of manuscripts these methods have been known. Huygens applied with great ( paper 4) virtuosity the by then classical methods of 17th century infinitesimal mathematics, and he needed all his ingenuity to reach a satisfactory solution. Leibniz ( the papers 1-2) and Bernoulli (paper 3), applying the new Calculus, found the solutions in a much direct way. In fact, the catenary was a test-case between the old and the new style in the study of curves, and only because the champion of the old style was a giant like Huygens, the test-case can formally be considered as ending in a draw."" (Grattan-Guiness in ""From the Calculus to Set Theory, 1630-1910."").The paper by JACOB BERNOULLI ( no. 5 offered here) is a milestone papers as it marks the invention of the ""SYSTEM OF POLAR COORDINATES"" with points located by reference to a fixed point and a line through that point. Although newton had earlier also devised such a coordinate system (in 1671), his work was not known, so that the credit for the discovery generally goes to Bernoulli. (Parkinson, Breakthroughs (1691).Further papers contained in this volume of Acta Eruditorum:DENYS PAPIN: Mecanicorum de Viribus Motricibus sententia, asserta a D. Papino adversius C.G.G. L. (Leibniz) objectiones. pp. 6-13. The plate lacks. - and Dion. Papini Observationes quaedam circa materias ad Hydraulicam spectantes. Pp. 208-213 a. 1 plate. This importent paper is part of the LEIBNIZ-PAPIN-CONTROVERSY.JACOB BERNOULLI: Specimen Calculi Differentialis in dimensione Parabolæ helicoidis, ubi de flexuris curvarum in genere, carundem evolutionibus. Pp. 13-22. The plate lacks. - and J.B. Demonstratio Centri Oscillationis ex Natura Vectis, reperta occassione eorum, quæ super hac materia in Historia Literaria Roterodamensi recensentur, articulo...Pp.317-321.LEIBNIZ: O.V.E. Additio ad Schediasma de Medii Resistentia publicatum in Actis mensis Febr. 1889. Pp. 177-178. and O.V.E. Quadratura Arithmetica Communis Sectionum Conicarum quæ centrum babent,...Pp. 178-182 a. 1 plate.TSCHIRNHAUS: Singularia Effecta Vitri Caustici bipedalis, quod omnia magno sumtu hactenus constructa specula ustoria virtute superat, per D.T. Pp. 517-520‎

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‎DAVY, HUMPHRY - THE DISCOVERY OF POTASSIUM AND SODIUM.‎

‎The Bakerian Lecture, on some new Phenomena of chemical Changes produced by Electricity,particularly the Decomposition of the fixed Alkalies, and the Exhibition of the new substances which constitute their bases" and on the general Nature of alkaline ...‎

‎(London, W. Bulmer and Co., 1808). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1808 - Part I. Pp. 1-44.‎

‎First printing of this importent historical paper in chemistry, in which Davy shows that electricity is capable of decomposing some alkalies, isolating two new substances and discovering potassium and sodium. Neville in his Historical Chemical Library vol. I, p.340, writes about this paper ""ONE OF THE GREAT CLASSIC RESEARCHES IN CHEMISTRY, in which Davy announced in this, his second Bakterian lecture, the isloation of metallic potassium and sodium by the electrolytic decomposition of their fused oxides.""""He (Davy) began his own electrical experiments...The results were spectacular. On October 6, 1807, the current passing through molten potash liberated a metal, which Davy called potassium. The little globules of shining metal tore the water molecule apart as it eagerly recombined with oxygen and the liberated hydrogen burst into lavender flame. Davy danced about in a delirium of joy. A week later he isolated sodium from soda.""(Asimow). The paper offered here describes these discoveries.""Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation, but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile, interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle, who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800, and his numerous discoveries were presented in his Bakerian lecture to the Royal Society on November 20, 1806.(A Source Book in Chemistry p. 243). - Wheeler Gift: 2514.‎

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‎"DAVY, HUMPHRY - THE DISCOVERY OF HYDROGEN TELLURIDE.‎

‎The Bakerian Lecture for 1809. On some new Electrochemical Researches, on various Objects, particularly the metallic Bodies, from the Alkalies, and Earth, and on some Combinations of Hydrogene. Read November 16, 1809.‎

‎(London, W. Bulmer and Co., 1810). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1810 - Part I. Pp. 16-74 and 2 engraved plates showing Davy's electrochemical apparatus for decomposing substances. The plates dampstained. Text fine and clean.‎

‎First appearence of this historical chemical paper, Davy' fifth Bakerian Lecture, in which he announced his discovery of hydrogen telluride.""Mr. Davy having from the commencement of his electro-chemical researches, communicated the several steps of his progress to the Society (The Royal Society), takes the present opportunity of reporting the results of his further inquiries under four principal heads. First, on the nature of the metals of the fixed alkalis. Second, on the nature of Hydrogen and composition of ammonia. Thirdly, on the metals of the earth"" and Fourthly he makes a comparison between the antiphlogistic doctrine, and a modified phlogistic hypothesis.""(Abstract). He further gives arguments for considering potassium and sodium, which he discovered in 1808, as a element.""Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation, but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile, interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle, who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800, and his numerous discoveries were presented in his Bakerian lectures."" - Wheeler Gift: 2518.‎

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‎"RAYLEIGH, LORD (J.W. STRUTT) and WILLIAM RAMSAY. - THE DISCOVERY OF ARGON.‎

‎Argon, a New Constituent of the Atmosphere. Received and Read January 31, 1895.‎

‎(London, Harrison and Sons, 1895). 4to. No wrappers as extracted from ""Philosophical Transactions"", Vol. 186 - I, Series A. Pp. 187-241 a. 8 textillustrations (apparatus). Fine and clean.‎

‎First printing of this importent paper in the history of chemistry, Lord Rayleigh's most famous discovery, announcing the discovery of this new gas, the first finding of one of the rare gases (inert gases) having unusual properties, and forming a distinct group in the periodic table, and all with zero valency.""The original paper in the ""Philosophical Transactions"" will undoubtly rank as a classic, the investigation having been a particularly brilliant ine."" (Ernst von Meyer in History of Chemistry). For this discovery Lord Rayleigh and W. Ramsay received the Nobel Prize (1904).After having made several measuring of the densities of gases, ""Rayleigh came across a curious puzzle. With oxygen, he always obtained the same density, regardless of how the oxygen might be produced, whether from one particular compound, from a second compound, or from the air. The situation was different with nitrogen. The nitrogen he obtained from air constantly showed a slightly higher density than the nitrogen he obtained from any of various compounds. Rayleigh could think of several ways in which the nitrogen obtained from air might be contaminated but none of the possibilities checked out experimentally. He was so frustrated that he went so far as to write to the journal ""Nature"" asking for suggestions. Ramsay, a brilliant Scottish chemist, asked permission to tackle the problem and received it. The upshot was that a new gas, somewhat denser that nitrogen, was discovered to exist in the atmosphere. It was named argon and it was the first of a series of rare gases of unusual properties whose existence had never been suspected.""(Asimow).Dibner, Heralds of Science No. 50 - Neville, Historical Chemical Library vol. II, p.358.‎

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‎"LOCKYER, JOSEPH NORMAN - THE DISCOVERY OF HELIUM.‎

‎Spectroscopic Observations of the Sun.- No. II. Received November 19,- Read November 19 and 26, 1868. (With additional notes Nov. 26, April 9, 1869, Oct. 10, 1869).‎

‎(London, Taylor and Sons, 1870). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1869, Vol. 159 - Part I. Pp. 425-444 and 2 lithographed plates (1 with the spectrum of helium, 1 with his spectroscope (not requiring eclipses to function)). Clean and fine.‎

‎First appearance of this milestone paper in chemistry, physics and astronomy, announcing the discovery of helium in the sun and naming it 'helium' for Helios, the Greek God of the Sun. In the same paper he demonstrates his invention of the spectroscope by which the prominences of the sun could be observed and studied without an eclipse by leading the light from the very edge of the sun through a prism. - Helium was not discovered on the earth before 1895 by William Ramsay, and it was Crookes who established its identity with the helium Lockyer observed in the spectrum of the sun.""This (the last discovery) was announced on the same day by the French astronomer Janssen, who was in India observing a total eclipse. As a result, the French government some ten years later struck a medallion showing the heads of both scientists.By that time, the two men had made a much more dramatic discovery at the same time, this time in cooperation. Janssen, studying the spectrum ofthe sun during the eclipse, had noted a fine line he did not recognize. he send a report on this to Lockyer, an acknowledges expert on solar spectra. Lockyer compared the reported position of the line with lines of known elements, concluding that it must belong to a yeat unknown element, possibly not even existing on the earth. He named the element, from the Greek word for the sun.""(Asimov).‎

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‎"WOLLASTON, WILLIAM HYDE. - THE DISCOVERY OF THE ELEMENT RHODIUM.‎

‎On a new Metal, found in crude Platina. Read June 24, 1804.‎

‎(London, Bulwer and Co., 1804). 4to. Without wrappers as extracted from ""Philosophical Transactions of the Royal Society of London."" Year 1804-Part II. Pp. 419-430. Clean and fine.‎

‎First appearance of the paper in which Wollaston announced his discovery of the metallic element Rhodium.""Dr. Wollaston dissolved a portion of crude platinum in qgua regia, and neutralized the excess acid with caustic soda. He then added salammoniac to precipitate the platinum as ammonium chloroplatinate, and mercurous cyanide to precipitate the palladium as palladium cyanide. After filteringoff the precipitate, he decomposed the excess mercurous cyanide inthe filtarate by adding hydrochloric acid and evaporating to dryness. When he washed the residue with alcohol, everything dissolved except a beautiful dark red powder, which proved to be a double chloride of sodium and a new metal, which because of the rose color of its salts, Dr. Wollaston named 'Rhodium'. He found that the sodium rhodium chloride could be easely reduced by heating it in a current of hydrogen, and that after the sodium chloride had been washed out, the rhodium remained as a metallic powder. he also succeeded in obtaining a rhodium button.""(Weeks: Discovery of the Elements. p. 104-05.)‎

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‎"HERSCHEL, JOHN W.F. - THE DISCOVERY OF THE IRON-PRINTING PROCESS.‎

‎On certain Improvements on Photographic Processes described in a former Communication, and on the Parathermic Rays of the Solar Spectrum. Received November 17, - Read November 17, 1842.‎

‎(London, Richard and John E., Taylor, 1843. 4to. No wrappers as extracted from ""Philosophical Transactions"" 1843 - Part I. Pp. 1-6.‎

‎First appearance of a pioneer-paper in the history of early photography, as Herschel here for the first time describes his discovery of the iron printing process with ammonio-citrate of iron by both methods, namely with blue lines on a white background and white lines on a blue ground.‎

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‎"HAHN, O. (OTTO). - THE DISCOVERY OF RADIOTHORIUM.‎

‎Über ein neues, die Emanation des Thoriums gebendes radioaktives Element.‎

‎Leipzig, S. Hirzel, 1905. No wrappers. Issued in ""Jahrbuch der Radioaktivität und Elekronik"", 2. Bd., Heft 3. Hahn's paper: pp. 233-264. Enntire issue: pp. 233-262 (= entire ""Heft 3""). Fine and clean.‎

‎First printing of this paper, which is Hahn's Habilitation paper, announcung his discovery of a new element in residues from a Ceylon mineral called Thorianite. He later showed that it is an intermediate disintegration product.""Because the sample (thorianite) was small, Ramsay proposed that Hahn confirm Marie Curie's determination of the atomic weight of radium by preparing it in some organic compounds (thereby greatly increasing the total amount being examined) and calculating the atomic weight from the measured molecular weights. Chance sometimes favors the unprepared mind, and Hahn, who familiarized himself with only the basic of radioactivity, followed the prescribed separationss technique and found himself the discovere of a new radioelement: radiothorium. The explanation was that the material given him came from an ore which contained a large percentage of thorium in addition to the radium. Thus, upon completion of the chemical procedure, not all the activity was confined in the radium-containg fraction"" indeed the nes subsyance in the remainder was several hundred thousand times more active than thorium and ultimately yielded the characteristic one.minute halflife of thorium emanation.""(DSB VI, p. 15). - Weeks, Discovery of the Elements,p. 308 ff.).‎

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‎"HERSCHEL, JOHN W.F. - DISCOVERY OF PRUSSIAN BLUE IN PHOTOGRAPHIC PROCESSES.‎

‎On the Action of the Rays of the Solar Spectrum on Vegetable Colours, and on some new Photographic Processes. Received June 15, - Read June 16, 1842.‎

‎(London, Richard and John E., Taylor, 1842.). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1842 - Part II. Pp. 181-214 and one double-page folded engraved plate.‎

‎First appearance of a pioneer-paper in the history of early photography in which Herschel announced some of his importent discoveries of the photographic printing processes, the process of photographic contact-printing in Prussian blue, brought to light just three years after Louis Daguerre and Henry Talbot had announced their independent inventions of photography in silver, using metal and paper substrates, respectively. and the photographic properties of red ferro sesquicyanuret of potassium.""This is the first recorded observation of Prussian blue being formed for a photographic purpose by the action of light on potassium ferricyanide, so it represents the moment of discovery of the first cyanotype process, although this name still lay in the future. The significance of this observation impressed Herschel sufficiently to mention it also in his general diary entry for 23 April 1842....""(Mike Ware in ""John Herschel's Cyanotype. Invention or discovery ?"").‎

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‎"LOMONOSOW (LOMONOSOV), MICHAELE (MIKHAIL). - THE DISCOVERY OF THE TRANSITION OF A METAL INTO PASSIVE STATE.‎

‎Dissertatio de Actione Menstruorum Chymicorum in Genere. (Considerations of the Action of chemical Solvents).‎

‎(Petropoli (St. Petersbourg), 1750). 4to. Uncut, without wrappers. Extracted from ""Novi Commentarii Academiae Scientiarum Imperialis Petropolitanae"", Tom. I. ad Annum 1747 et 1748. Pp. 245-266 a. 1 engraved plate (ad. p. 251). Clean and fine.‎

‎First appearance of a groundbreaking paper in chemistry in which Lomonosov describes his discovery of the transition of a metal into passive state, and this is the first scientific description of this phenomena. He observed and described fast termination of the dissolution of iron in concentrated nitric acid, and attributed this to a change in the solvent properties.""Lomonosov employed corpuscular mechanics in chemical explanations more extensively than Boyle had done. Treating chemical compounds as particles in adhesion, he held that ""adhesion is eliminated and renewed by means of motion.....since no change in a body can take place withouy motion"". He attempted to apply these theories to chemical phenomena - although he was limited to speculation- in papers on the action of chemical solvents in general..""(DSB VIII, p. 469).""Lomonosov was founder of Russian science, and he would be universally recognized as a great pioneer of science had he been born a West European. He was famous also for his literary works, including poems and dramas. In 1755 he wrote a Russian Grammar that reformed the language and in the same year he helped found the University of Moscow. In 1760 he published the first history of Russia.""(Isaac Asimov).‎

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‎COURTOIS, BERNARD ET AL. - THE DISCOVERY OF IODINE.‎

‎Découverte d'une substance nouvelle dans le Vareck. (Annoncée par M. Clément). - Sur un nouvel acide formé avec la substance découverte par M. Courtois. - Note Sur la combinaison de l'iode avec l'oxigène" Par M. Gay-Lussac. - Lettre de M. Humphry ...‎

‎Paris, J. Klostermann, 1813. Contemp. hcalf. Spine gilt. A few scratches to binding. In: ""Annales de Chimie, ou Recueil de Mémoires concernant la Chemie"" Tome 88. - 336 pp. (the entire volume offered). Pp. 304-310, 311-318, 319-321 a. 322-329. Scattered brownspots.‎

‎First printing of this paper announcing the discovery of Iodine. Courtois found this substance, which he suspected to be a new element, while burning algae in order to obtain sodium and potassium compounds. Although Courtois discovered the element in 1811, the announcement of it was not made until two years later after he had turned it over to Charles Desormés and Nicolas Clément.""The first publication on iodine are somewhat confusing. Courtois's research is found in a paper attributed to him (the paper offered) but actually the work of Clément.... was followed by an anonymous article (the second paper offered). Gay-Lussac. who repeated and extended Courtios's work, was responsible for this paper. Courtois himself published nothing. These two articles were immediately followed by short contributions of Gay-Lussac and Humphry Davy on the new element (third and fourth paper offered). Gay-Lussacs views (none too flattering to Davy) on the history ofthe discovery of iodine appeared in his ""Mémoire sur l'iode"" (1814).""(DSB III, p. 455). - Weeks ""Discovery of the Elements"", pp. 257-262.The volume contains further importent papers in chemistry, Guyton de Morveau ""Sur la chaux maigre"", ""Sur le dissolvant des pierres biliaires"", an importent paper by Chevreul on animal fats ""Recherches chimiques sur plusieurs corps gras, et particulierement sur leurs combinaisons avec les alcalis"", Berzelius's papers ""Mémoires sur la compositions des fluides animaux"" (first edition in French) + Suite (first edition), Parmentier etc. etc.‎

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‎VAUQUELIN, (NICOLAS) - THE DISCOVERY OF BERYLLIUM.‎

‎De l'Aigue marine, ou Béril" et découverte d'une terre nouvelle dans cette pierre. Lue à l'Institut, le 26 Pluviose, an 6. (+) Notice sur la terre du Béril, pour servir de suite au premier mémoire sur le méme objet. (+) Analyse De l'Émeraude du Pé...‎

‎Paris, Fuchs et Guillaume, An VIe. (1798). Contemp. hcalf. Spine gilt. Very slightly rubbed. Small stamps on verso of titlepage. In: ""Annales de Chimie, ou Recueil de Mémoires concernant la Chemie"" Tome 26. - 340 pp. a. 1 engraved plate.(the entire volume offered). Vauquelin's papers: pp. 155-169, pp. 170-177 a. pp. 259-265. Some brownspots to the first and last leaves, otherwise fine and clean.‎

‎First printing of the papers in which Vauquelin describes and announces his discovery of Beryllium.""The discovery of beryllium resulted from the Abbé Haüy's observation of the close similarity and probable identity of beryl and the emerald. At his suggestion Vauquelin made some very careful chemical analyses of these two minerals, and found in 1798 that they are indeed identical, and that they contain a new earth, which he named glucina, but which is now known as beryllia. The metal was isolated thirty years later by Wöhler and Bussy independently.....At the suggestion of the editors of the ""Annales de Chemie...."", he called the new earth 'glucina', meaning sweet."" (Weeks in ""Discovery of the Elements"", p. 153-54). - Parkinson ""Breakthrough"" 1798 C.The volume contains other importent papers in the history of chemistry, Hassenfratz ""De l'Areométrie"" + ""Suite..."" 2 Paprs., Berthollet, Chaptal, Guyton, Fourcroy, Priestly (first app. in French) etc.‎

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‎"VAUQUELIN, (NICOLAS) - THE DISCOVERY OF CHROMIUM.‎

‎Sur une nouvelle substance métallique contenue dans le plomb rouge de Sibérie, et qu'on propose d'appeler Chrôme, à cause de la propriété qu'il a de colorer les combinaisons ou il entre. Lu à la premiere classe de l'Institut national, le 11 Brumai...‎

‎Paris, Fuchs et Guillaume, An VIe. (1798). Contemp. hcalf. Spine gilt. Very slightly rubbed. Small stamps on verso of titlepage. In: ""Annales de Chimie, ou Recueil de Mémoires concernant la Chemie"" Tome 25. - 335,(3) pp., 2 engraved folded plates and 1 folded table..(the entire volume offered). Vauquelin's papers: pp. 21-32 a. pp. 194-204. Some brownspots to the first and last leaves, otherwise fine and clean.‎

‎First printing of the papers in which Vauquelin describes and announces his discovery of Chromium. The first paper was simultaneously printed in Mem.de l'Institut. Because of its many coloured compounds Fourcroy and Haüy suggested the name 'chromium' for the new metal. (Greek, chroma-colour).In 1797, Vauquelin began his own studies of Siberian red lead. He was convinced that the mineral contained a new element. None of the elements then known could account for his results. He reported ""a new metal, possessing properties entirely unlike those of any other metal."" A year later, Vauquelin was able to isolate a small sample of the metal itself. He heated charcoal (nearly pure carbon ) with a compound of chromium, chromium trioxide (Cr 2 O 3 ). When the reaction was complete, he found tiny metallic needles of chromium metal. DSB XIII, p. 597 - Parkinson ""Breakthrough"" 1798 C.The volume contains other importent papers in the history of chemistry, Guyton ""Examen de quelques propriétés du Platine"" a. ""Examen de quelques critiques de la nomenclature de chimistes francais"", Chaptal ""Observations sur la fabrication de l'acétite de cuivre (verd-de-gris) etc.‎

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‎"FARADAY, M. (MICHAEL). - THE DISCOVERY AND ISOLATION OF BENZENE.‎

‎On new compounds of carbon and hydrogen, and on certain other products obtained during the decomposition of oil by heat. Read June 16, 1825.‎

‎(London, W. Nicol, 1825). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1825 - Part II. Pp. 440-466. Clean and fine.‎

‎First appearance of this remarkable paper in which Faraday announces his discovery of Benzene. Berzelius described this research as ""without doubt one of the most importent which has enriched chemistry during 1825.""""The first public announcement of the discovery of benzene, the greatest chemical discovery made by Faraday. Originally named by him ""bicaburet of hydrogen"", benzene is the parent substance of all aromatic compounds. It constitutes the basis of thousands of organic compounds, dyes, perfumes, and medicinal products, as well as many polymers and structural materials. The discovery of benzene led to the creation of numerous chemical companies and the manufacture of materials previously unknown. This paper is a thourough study of the physical and chemical properties of benzene.""(Neville I, p. 443). - Parkinson ""Breakthrough"" 1825 C.‎

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‎"GAY-LUSSAC, (JOSEPH) et LOUIS JACQUES THENARD. - THE DISCOVERY OF BORON.‎

‎Sur la décomposition et la recomposition de l'acide boracique.‎

‎Paris, Chez Mad. Ve. Bernard, 1808 Contemp. hcalf., gilt spine. Some scratches to binding.. Verso of titlepage and plates with small stamps.In: ""Annales de Chimie"" Vol. 68. - 358 pp. a. 3 engraved plates. (The entire volume offered). Gay-Lussac's a. Thenard's paper: pp. 169-174.‎

‎First announcement of the results that they had obtaines by treating boric acid with potassium, showing that acid is composed of a combustible substance and oxygen. ""Before regarding their proof (of the existance of a new element) as complete Gay-Lussac and Thenard wished not only to decomposed boric acid, but to recompose it. On November 30 of the same year they were able to state in the 'Annales de Chemie et de Physique"" (the paper offered) that ""the composition of boracid s no longer problematical. In fact, said they, ""we decompose and we recompose this acid at will"" (Weeks ""Discovery of the Elements"", p. 160). - Parkinson ""Breakthroughs"", 1808 C. - Bunch, 1808.The volume contains other importent paper, Davy's famous paper on electrolysis in first French translations, Gayton-Morveau""Description d'un hygrometre pour le gaz..."", d'Arcet ""Observations sur la potasse et sur la soude préparées à l'alcool"" etc.‎

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‎"BROWN, ROBERT. - THE DISCOVERY OF ""BROWNIAN MOTION""‎

‎Mikroskopische Beobachtungen über die im Pollen der Pflanzen enthaltenen Partikeln, und über das allgemeine Vorkommen activer Molecüle in organischen und unorganischen Körpern"" (Unterdem Titel: ""A brief Account of Microscopical Observations made in th...‎

‎Leipzig, Johann Ambrosius Barth, 1828. Without wrappers as issued in ""Annalen der Physik und Chemie. Hrsg.von Poggendorff"", Bd. 14, Zweites Stück. (=Jahrgang 1828, zehntes Stück). Pp. 191-306 a. 3 engraved plates. (the entire issue offered (Heft 2) together with the titlepage to 14. Band). Brown's paper: pp. 294-313. Clean and fine. Small stamp on verso of titlepage.‎

‎First appearance in German of this monumental paper in atomic theory and kinematics, as it was the first evidence for atomism that was an observation rather than a deduction from abstract principles.""In 1827 as he was viewing a suspension of pollen in Water under the microscope, he noted that the individual grains were moving about irregularly. This, he thought, was the result of the life hidden within the pollen grains. However, when he studied dye particles (indubitably nin-livin) suspended in water, he found the same erratic motion. This has been called ""Brownian motion"" ever since and Brown could merely report on the observation. He had no explanation for it. Nor had anyone else until the development of the kinetic theory of gases by men such as Maxwell a generation later. It seemed plain. after Maxwell and especially after the work of Einstein and Perrin a half century after Maxwell, that the Brownian Motion was actually a visible effect of the fact that water was composed of particles. It was the first evidence for atomism that was an observation rather than a deduction."" (Asimov).The issue contains other importent papers by C.. Naumann, G. Magnus, Th. Saussure ""Kohlensäuregas in der Atmosphäre"" andothers.PMM: 290 (the English paper from 1828) - Sparrow, Milestones of Science No 31. - Magie ""A Source Book in Physics p. 251-255. - Dibner, Heralds of Science No 156.‎

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‎"STROMEYER (STROHMEYER), FRIEDRICH. - THE DISCOVERY OF CADMIUM.‎

‎Ueber das Kadmium. (Eine Darstellung der Resultate des ersten Theils seiner Untersuchungen über dieses, vo ihm in dem Zink und den Zinkoxyden entdeckte, neue Metall.).‎

‎Leipzig, Johann Ambrosius Barth, 1819. Without wrappers as issued in ""Annalen der Physik. Hrsg. von Ludwig Wilhelm Gilbert"", Bd. 60 Heft 2 (= Jahrgang 1818, zehntes Stück). Pp. 113-218 a. 1 engraved plate (map). The entire issue offered (Heft 2). Stromeyer's paper pp. 193-210. Clean and fine.‎

‎First appearance of Strohmeyer's account of his discovery of Cadmium. The history of its discovery was very complicated as some other laid claim to its discovery.Stromeyer was inspector general of apothecaries in Hannover. ""In 1817, fulfilling the duties of his office, he came across an apothecary's shop in which a bottle labeled zinc oxide contained zinc carbonate. Following this up, Stromeyer found himself interested in zinc carbonate, which turned yellow on strong heating as though it contained iron as an impurity, yet it contained no iron. He traced the yellow to an oxide not of zinc but of a hitherto unknown metal rather like it chemically. He named it cadmium for a zinc ore in which it is usually found accompanying the zinc.""(Asimov).Weeks ""Discovery of the Elements"", pp. 135-39.‎

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‎"PLÜCKER, (JULIUS). - THE DISCOVERY OF CATHODE RAYS.‎

‎Ueber die Constitution der elektrischen Spectra der verschiedenen Gase und Dämpfe. (+) Nachtrag zu der Abhandlung über die Consstitution der elektrischen Spectra der verschiedenen Gase und Dämpfe. (2 papers).‎

‎Leipzig, Johann Ambrosius Barth, 1859. Without wrappers as issued in ""Annalen der Physik und Chemie. Hrsg.von Poggendorff"", Bd. 107, Viertes Stück.(= Heft No. 8 of 1859). (The entire issue offered (Heft 4 of vol. 107 with titlepage to vol. 107). Pp. 497-660. - Plücker's papers: pp. 497-539 a. 638-643. Clean and fine.‎

‎First printing of this milestone paper describing Plückers first observations on Cathode Rays, which he called ""the beautiful and mysterious green glow"", and produced by discharges in tubes exhausted by means of the Geissler pump. These importent observations lead directly to Röntgens discovery of the Röntgen Rays.""Cathode rays were first observed by Julius Plücker in 1859 (the paper offered). They are rays which are found in the neighbourhood of the point of exit of an electrical current passing through a Geissler tube. These rays stimulated intense interest and experiment. William Crookes greatly improved these discharge tubes and intensified the degree of rarification of gases within them. The tubes in this form is known as Crookes tube. Crookes declared his conciction that the cathode rays represented matter in a fourth, hitherto unobserved form....It was reserved for J.J. Thomson (in 1908) to discover the true nature of the cathode rays.""(PMM no 386).‎

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‎"SOUBEIRAN, EUGÈNE - THE DISCOVERY OF CHLOROFORM.‎

‎Recherches sur quelques Combinaisons du Chlore.‎

‎Paris, Crochard, 1831. No wrappers as extracted from ""Annales de Chimie et de Physique"", 2. Series, Tome 48. Titlepage to vol. 48. Pp. 113-157. A few brownspots, but fine. Small stamps on verso of titlepage.‎

‎First appearance of an importent paper in chemistry and medicine as it for the first time relates the finding of Chloroform, which some years later was proved to have anaesthetic effects and was introduced in chirurgy in 1848 by Simpson.Justus von Liebig, Souberain and Guthrie independently discovered Chloroform in 1831, but Souberain was the first to publish his results. - Garrison & Morton No. 1851. - Gedeon ""Science and Technology in Medicine"" 36.7.‎

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‎"SCHWANN, THEODOR. - THE DISCOVERY OF PEPSIN, THE FIRST KNOWN ANIMAL ENZYME.‎

‎Ueber das Wesen des Verdauungsprocesses. (On the essence of digestion).‎

‎(Leipzig, Johann Ambrosius Barth, 1836). Without wrappers. In ""Annalen der Physik und Chemie. Hrsg. von J.C. Poggendorff"", Band 38, No. 6 (= Zweyte Stück). Titlepage to Vol. 38. Pp. 241-450 a. 3 engraved plates.(Entire issue offered, Heft No. 6, Bd. 38). Schwann's paper: pp. 358-364. Clean and fine.‎

‎First appearance of an importent paper in the history of biology, in which Schwann describes his discovery and isolation of pepsin, the substance in the stomach that aids digestion of eggwhite. It is the FIRST KNOWN ANIMAL ENZYME. The paper appeared at the same time in ""Archiv für Anatomie, Physiologie und Wissenschaftliches Medicin""Theodor Schwann (1810-1882) was a great German physiologist, pathologist, and experimenter. One of the founders of the cell doctrine and of the idea of the living nature of yeast. Born at Neuss, near Düsseldorff. A catholic, educated in the Jesuit Gymnasium in Cologne. Intended for the church but took to medicine. He was a pupil of Johannes Müller and a collegueand lifelong friend of J. Henle, the anatomist. In Berlin Schwann was Johannes Müller's assistent for five years, and it was then that he discovered pepsin in 1836 (the paper offered).Parkinson ""Breakthroughs"" 1836 B.The issue contains other importent papers by Seebeck, Matteucci, Marchand, G. Magnus ""Ueber die Wirkung des Ankers auf Elektromagnete und Stahlmagnete"", Schönbein, J. Müller ""Ueber die Structur und die chemischen Eigenschaften der thierischen Bestandtheile der Knorpel und Knochen"" + Nachtrag., Forchhammer ""Der kopaische See und seine unterirdischen Abzugskanäle.."" with a map.‎

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‎"RITTER, (JOHANN W.). - THE DISCOVERY OF ""CHEMICAL RAYS"" - ULTRAVIOLET LIGHT AND RADIATION.‎

‎Announcing his discovery of ultraviolet light ""Von den Herren Ritter und Bückmann. - - Am 22sten Febr. habe ich auch auf der Seite des Violetts im Farbespectrum, ausserhalb desselben, Sonnenstrahlen angetroffen....‎

‎Halle, Rengerschen Buchhandlung, 1801. Without wrappers as published in ""Annalen der Physik. Herausgegeben von Ludwig Wilhelm Gilbert"", Bd. 7, Viertes Stück. The entire issue offered (=Heft 4). Pp. 387-528. Ritter's announcement p. 525. With titlepage to volume 7. Clean and fine. Titlepage a bit shavedin inner margin.‎

‎First printing of Ritter's announcement of his discovery of ultraviolet light in a halfpage letter addressed to Gilbert's Annalen. With that discovery, it became clear that visible light represents no more than a fraction of a continous spectrum.A year earlier, in 1800, William Herschel discovered infrared light. This was the first time that a form of light beyond visible light had been detected. After hearing about Herschel's discovery of an invisible form of light beyond the red portion of the spectrum, Ritter decided to conduct experiments to determine if invisible light existed beyond the violet end of the spectrum as well. He had heard that blue light caused a greater reaction in silver chloride than red light did. Ritter decided to measure the rate at which silver chloride reacted to the different colors of light. He directed sunlight through a glass prism to create a spectrum. He then placed silver chloride in each color of the spectrum and found that it showed little change in the red part of the spectrum, but darkened toward the violet end of the spectrum. Johann Ritter then decided to place silver chloride in the area just beyond the violet end of the spectrum, in a region where no sunlight was visible. To his amazement, this region showed the most intense reaction of all. This showed for the first time that an invisible form of light existed beyond the violet end of the visible spectrum. This new type of light, which Ritter called Chemical Rays, later became known as ultraviolet light or ultraviolet radiation (the word ultra means beyond). - Parkinson, Breakthroughs: 1801 P.‎

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‎HERSCHEL, WILLIAM. - THE DISCOVERY OF INFRARED RADIATION.‎

‎Untersuchungen über die wärmende und die erleuchtende Kraft der farbigen Sonnenstrahlen Versuch über die nichht-sichbaren Strahlen der Sonne und deren Brechbarkeit" und Einrichtung grosser Teleskope zu Sonnenbeobachtungen.‎

‎Halle, Rengerschen Buchhandlung, 1801. Without wrappers as published in ""Annalen der Physik. Herausgegeben von Ludwig Wilhelm Gilbert"", Bd. 7, Zweites Stück. The entire issue offered (=Heft 2). Pp. 137-264 a. 2 folded engraved plates. Herschels papers: pp. 137-156. The plate depicts Herschel's experimental arrangements.‎

‎First appearance in German of Herschel's epochal announcement of his discovery of infrared light in 1800. This was the first time that a form of light beyond visible light had been detected. The paper offered is the German translation of the main parts of Herschel's paper ""An Investigation of the Powers of Prismatic Colours to Heat and Illuminate Objects"".""In 1800 he tested various portions of the sun's spectrum by thermometer to see if he could find interesting differences in the amount of heat the different colors delivered. He did, but in a rather unexpected way, for he found that the temperature rise was highest in no color at all, at a spot beyond the red end of the spectrum. He concluded that the sunlight contained invisible light beyond the red. This is now called infrared radiation. The following year Ritter was to extend the visible spectrum in the other direction.""(Asimov).Parkinson ""Breakthroughs"" 1800 P.‎

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‎"RITTER, (JOHANN W.). - THE DISCOVERY OF ULTRAVIOLET LIGHT.‎

‎Versuche über das Sonnenlicht.‎

‎Halle, Rengerschen Buchhandlung, 1803. Without wrappers as extracted from ""Annalen der Physik. Herausgegeben von Ludwig Wilhelm Gilbert"", Jahrgang 1802, Bd. 12, Zwölftes Stück. Pp. 409-416. Titlepage to vol. 12.‎

‎This is Ritter's first expositon of his discovery of ultraviolet light. It was announced the year before in a halfpage letter addressed to Gilbert's Annalen and printed in the Annalen. With that discovery, it became clear that visible light represents no more than a fraction of a continous spectrum.A year earlier, in 1800, William Herschel discovered infrared light. This was the first time that a form of light beyond visible light had been detected. After hearing about Herschel's discovery of an invisible form of light beyond the red portion of the spectrum, Ritter decided to conduct experiments to determine if invisible light existed beyond the violet end of the spectrum as well. He had heard that blue light caused a greater reaction in silver chloride than red light did. Ritter decided to measure the rate at which silver chloride reacted to the different colors of light. He directed sunlight through a glass prism to create a spectrum. He then placed silver chloride in each color of the spectrum and found that it showed little change in the red part of the spectrum, but darkened toward the violet end of the spectrum. Johann Ritter then decided to place silver chloride in the area just beyond the violet end of the spectrum, in a region where no sunlight was visible. To his amazement, this region showed the most intense reaction of all. This showed for the first time that an invisible form of light existed beyond the violet end of the visible spectrum. This new type of light, which Ritter called Chemical Rays, later became known as ultraviolet light or ultraviolet radiation (the word ultra means beyond).‎

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‎"PELTIER, JEAN CHARLES A. - DISCOVERY OF THE ""PELTIER-EFFECT""‎

‎Nouvelle Expériences sur la Caloricité des courans électriques.‎

‎(Paris, Crochard, 1834). No wrappers. In: ""Annales de Chimie et de Physique"", 2. Series, Tome 56, Cahier 4 (last issue of tome 56). Entire issue offered. Pp. 337-444. Peltier's paper: pp. 371-386. The text calls for a plate, but not present here.‎

‎First printing of the paper in which Peltier describes his discovery of the ""Peltier-Effect"", the thermo-electric cooling and heating of an electrical junction dependent on the direction of the current.""Stimulated by the work of Nobili, Peltier constructed a sensitive galvanometer to measure the conductivities of antimony and bismuth for small currents. Peltier's use of small samples of these nonductile materials was fortunate because the anomalous behavior of these materials led him to construct a thermoelectric thermoscope and to measure the temperature distribution along a series of thermocouple circuits. He discovered that a cooling effect can take place at one junction and an excessive heating at the other. He then confirmed this discovery by using an air thermometer in place of the thermoscope. Peltier did not pursue the effect he had discovered, and its importence was not fully recognized until after the thermodynamic work of William Thomson twenty years later.""(DSB X, p. 500).Wheeler Gift no 2684. - Ronald's Library, p. 389. - Parkinson ""Breakthroughs"" 1834 P.‎

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‎"WÖHLER, F. und J. LIEBIG. - THE DISCOVERY OF ""EMULSIN"" A MAIN WORK IN ORGANIC CHEMISTRY.‎

‎Ueber die Bildung des Bittermandelöls. (+) Vorschlag zur Einführung eines neuen Arzneimittels anstatt des destillirten Kirschlorbeer- und Bittermandelswassers. (+) Ueber Marcet's Xanthic-Oxyd. (3 papers all by Wöhler u. Liebig).‎

‎Leipzig, Johann Ambrosius Barth, 1837. Without wrappers as issued in ""Annalen der Physik und Chemie. Hrsg.von Poggendorff"", Bd. 41, Zweites Stück. (Entire issue No 6 offered). Titlepage to vol. 41. Pp. 225-448 a. 2 folded engraved plates. Wöhler & Liebig's papers: pp. 345-366, pp. 366-374 a. pp. 393-397. Clean and fine.‎

‎First appearance of this classic paper in organic chemistry in which Wöhler and Liebig showed how Amygdalin could be decomposed by a vegetable emulsion, the first example of a glycoside.""The conclusions which you have drawn from the investigation of bitter-almond oil,"" wrote Berzelius to Liebig and Wöhler, ""are certainly the most importent which have so far been reached in the domain of vegetable chemistry, and give promise of shedding an unexpected light over this part of the science...The facts which you have set forth inspire such reflections that they may be regarded as the dawn of a new day in vegetable chemistry.""(Berzelius-Wöhler Briefwechsel).""During the years that Liebig was preoccupied with the ether theory and with organic acids, he also carried out two importent investigations with Wöhler. In october 1836 Wöhler wrote that he had discovered a way to transform amygdalin to oil of bitter almonds and hydrocyanid acis, by distilling it with manganese and sulfuric acid, and he invited Liebig to join in pursuing the topic. Two days later he made a more remarkable discovery. It had occurred to him that perhaps thetransformation of amygdalin could be effected by the albumin in the almonds, in a manner similar to the action of yeast in sugar...Wöhler suspected that the decomposition was an example of what Berzelius had recently defined as catalysis. Liebig and Wöhler then divided up the detailed examination of the properties and composition of amygdalin. They precipitated from the emulsion of almonds a substance which when dissolved retain its action. They named the active substance ""emulsion"". Its effectiveness in very small quantities confirmed that it acted like yeast.""(DSB VIII, p. 342).‎

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‎"BALARD, ANTOINE JÉROME. - THE DISCOVERY OF THE ELEMENT BROMINE‎

‎Mémoire sur une Substance particulière contenue dans l'eau de la mer (le brôme).‎

‎(Paris, Crochard, 1826). Without wrappers. In: ""Annales de Chimie et de Physique, par Gay-Lussac et Arago"", tome 32, Sec. Series, Cahier 4. Pp. 337-443 a. 1 fodled engraved plate. (The entire issue offerd). Balard's paper: pp. 337-84.‎

‎First printing of Balard's famous memoire in which he records his discovery of the new element Bromine (le brôme). While he was studying the flora of a salt marsh, he notized a deposit of sodium saulfate which had crystallized out in a pan containing mother liquer from common salts. ""In an attempt to find a use for the waste liquers he performed a number of experiments, and notized that when certain reagents were added, the mother liquer bacame brown. His investigation of this phenomenon,...ked to the remarkable discovery....(Weeks p. 264).""The discovery of a new chemical element by a young and obscure provincial pharmacist caused a sensation in Paris. Balard's achievemnt was recognized by the Academie des Sciences and he was awarded a medal by the Royal Society of London.""(DSB I, p. 416).""The discovery of bromine is a very importent acquisition to chemistry, and gives M. Balrad honorable rank inthe career of the sciences. We are of the opinion that this young chemist is every way worthy of the encouragement of the Academy, and we have the honour to propose that his memoir shall be printed in the ""Recueil des Savants Étrangers"" (The report from the French Academy, signed by Vaugelin, Thenard, and Gay-Lussac).‎

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‎"SCHMIDT, G.C. - THE DISCOVERY THAT THORIUM IS RADIOACTIVE.‎

‎Ueber die von den Thorverbindungen und einigen andern Substanzen ausgehende Strahlung.‎

‎Berlin, J.A. Barth, 1898. No wrappers. In ""Annalen der Physik"", Neue Folge Band 65, No 5. Pp. 1-240.. (Entire issue offered, No.5). Titlepage to vol. 65. Stamp on titlepage. Schmidt's paper: pp. 141-151, textillustr. A tear to inner lower corners of pp. 24-32. (not affecting Schmidt's paper). Clean and fine.‎

‎First printing of Schmidt's full exposition, in which he describes his discovery of the radioactivity of Thorium. Schmidt and Marie Curie independently demonstrated the radioactive quality, but Schmidt's demonstration took place a few months before Curie's. The discovery was announced, but not described in full, in a short message published in ""Verhandl. d. Phys. Gesellsch. zu Berlin, 1898.""Schmidt made his discovery while examining ""many elements and compounds"" in an effeort to determine whether any of the rays that were emitted bore a resemblance to those that Henri becquerel had found emerging from uranium and uranium compounds. He located only one such element, thorium, and immediately conducted absorption, ionization, reflection, refradction, and poklarization studies to determine the characteristics of its rays. Having combined a misinterpretation of Becquerel's with one of his own, Schmidt concluded that thorium rays most resembled Röntgen rays - a conclusion that soon required revisoln in view of the researches of Marie Curie and Ernest Rutherford.""(DSB XII, p. 191.‎

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‎"PELLETIER, PIERRE et JOSEPH CAVENTOU. - THE DISCOVERY OF STRYCHNINE.‎

‎Note sur un nouvel Alcali (Lu à l'Academie des Sciences le 10 août 1818. (+) Mémoire Sur un nouvel Alcali végétal (la Strychine) trouvé dans la fève de Saint-Ignace, la noix vomique, etc. (Lu à l'Academie des Sciences le 14 décembre 1818).‎

‎(Paris, Crochard, 1818,1819). No wrappers. In: ""Annales de Chimie et de Physique, Par MM. Gay-Lussac et Arago."", tome 8 (Cahier 3) a. 10 ( Cahier 2), pp. 225-336 and pp. 129-240. (Entire issues offered). Pelletier & Caventou's papers: pp. 323-324 (tome 8) and pp. 142-176 (tome 10). A few scattered brownspots.‎

‎First printing of these classic papers in chemistry in which the authors announced their discovery of Strychnine. This was the first alkali of vegetable origin to be discovered after morphine. This discovery (and their discovery of chlorophyll) brought them international fame. The first small paper contains the announcement of the discovery and the second long memoir contains the elaborate exposition of the discovery.""Strychnine was only the second alkaloid to be extracted, the first was morphine. Pelletier and Caventou wanted to name their new alkaloid vauqueline after Nicolas Vauquelin, one of their associates who had refined the technique of ether extraction for use in isolating alkaloids. However, the officers of the Académe des Sciences in Paris rejected the idea on the grounds that a respected scientist’s name should not be paired with a deadly poison. In addition to strychnine the pair isolated other important compounds from plants including caffeine, chlorophyll and the anti-malaria drug quinine. (Paul L. Burnham).Parkinson:""Breakthroughs"", 1818 C. - Garrison & Morton: 1846.The first issue also contains their importent memoir ""Examen chimique de la Cochenillee et de sa matière colorante"", pp. 250-287 which describes how they obtained crotonic acid from croton oil and analyzed carmine in the cochineal.‎

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‎"ÅNGSTRÖM, A.J. (ANDERS JONAS). - THE DISCOVERY OF HYDROGEN IN THE SUN.‎

‎Ueber die Fraunhofer'schen Linien im Sonnenspectrum. (Mitgetheilt vom Hrn. verf. aus d. Oefversigt af K. vet. Acad. Förhandl."" 1861, No 8, nebst einem späteren Zusatz).‎

‎Leipzig, Johann Ambrosius Barth, 1862. Without wrappers as issued in ""Annalen der Physik und Chemie. Hrsg. von J.C. Poggendorff"", Vierte Reihe Bd. 27 (117), Stück Zwei, No. 10. The entire issue offered. Titlepage to vol. 27. Pp. 193-352 a. 1 engraved plate. Ångströms paper: pp. 290-302.‎

‎First appearance in German of Ångström's famous paper in which he announced the discovery of hydrogen in the atmosphere of the sun and in which he also confirmed the probable existence of of other elements there. The paper appeared in ""Oefversigt af K. Vet. Acad. Förhandl."" in 1861. The German paper here is expanded. At the same time it was translated into English and publishe as ""On the Fraunhofer Lines Visible in the Solar Spectrum"".Ångström was one of the early formulators of the science of modern spectroscopy" he wrote extensively on terrestrial magnetism, the conduction of heat, and especially spectroscopy. He published a monumental map of the normal solar spectrum that expressed the length of light waves in units of one ten-millionth of a millimeter, a unit of length now known as the angstrom. He discovered that hydrogen is present in the sun's atmosphere, and he was the first to examine the spectrum of the aurora borealis.‎

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‎"DAVY, HUMPHRY. - THE DISCOVERY OF THE ANAESTETHIC EFFECTS OF ""LAUGHING GAS""‎

‎Athembarkeit des sauerstoffhaltigen Stickgas"" aus einem Briefe H.Davy's an Will. Nicholson. (+) Nachricht von einigen merkwürdigen Versuchen Davy's. (Aus einem Briefe Humphry Davy's an Will. Nicholson).‎

‎Halle, Rengerschen Buchhandlung, 1799, 1800. Without wrappers extracted from ""Annalen der Physik. Herausgegeben von Ludwig Wilhelm Gilbert"", Bd. 2. p. 483 (one page). and Bd. 6, pp. 105-115. Some scattered brownspots.‎

‎First German translation of Davy's announcement (the announcement on 1 page) of his discovery of the unusual, anaesthetic, effects of nitrous oxide which, on being inhaled, gave rise to a giddy, intoxicated feeling. On announcing his discovery he says, that he will publish a paper discribing the experiments with the gas, later. This is the paper offered here, also in the first German version. Both the announcement and the paper were issued in the ""Annalen"" the same year as they appeared in Nicholson's Journal.The gas was first synthesized by English natural philosopher and chemist Joseph Priestley in 1772, who called it phlogisticated nitrous air.""Following Priestley's discovery, Humphry Davy of the Pneumatic Institute in Bristol, England, experimented with the physiological properties of the gas, such as its effects upon respiration. He even administered the gas to visitors to the institute, and after watching the amusing effects on people who inhaled it, coined the term 'laughing gas'! Davy even noted the anaesthetic effects of the gas: ""As nitrous oxide in its extensive operation appears capable of destroying physical pain, it may probably be used with advantage during surgical operations in which no great effusion of blood takes place"".(Wikipedia).""Davy discovered the anaesthetic properties of nitrous oxide and suggested its use during surgiical operations, a suggestion which was not turned to useful account until 1844.""(Garrison & Morton, 5646, not mentioning the announcing of its discovery in 1799).‎

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‎"FARADAY, MICHAEL. - THE DISCOVERY OF ELECTRO-MAGNETIC INDUCTION (PMM 308) - FRENCH VERSION.‎

‎Recherches expérimentales sur l'Electricité. I-V. (I. Sur l'induction des courans l'èlectriques. II. Sur le développement de l'électricité par le magnetisme. III. Sur une nouvelle condition électrique de la matière. IV. Sur les phénomènes magnét...‎

‎Paris, Crochard, 1832. Contemp. hcalf., gilt spine, light wear along edges. In: ""Annales de Chimie et de Physique, Par MM. Gay-Lussac et Arago."", tome 50, Series 2. (Entire volume offered). 448 pp. 2 folded engraved plates. Faraday's papers: pp. 5-67 a. pp. 113-162.‎

‎First French editions of the 2 first memoirs of Faradays groundbreaking researches on electricity, constituting the first 2 papers of his ""Experimental Researches in Electricity"", and containing his fundamental discovery of electromagnetic induction, THE FOUNDATION OF NEARLY ALL THE ELECTRICITY IN USE TODAY. In 1820 Oersted had generated magnetism from electricity, Faraday here finds the opposite effect, generating electricity by magnetism. He also described the first electrical generator (second paper). THESE PAPERS ARE SOME OF THE GREAT CLASSICS OF CHEMISTRY AND PHYSICS.""Faraday demonstrated this theory involving the lines of force....by inserting a magnet into a coil of wire attached to a galvanometer. While the magnet was being inserted or removd, current flowed through the wire. If the magnet was held stationary and the coil moved over it one way or the other, there was current in the wire. In either case the magnetic lines of force about the magnet were cut by the wire.If the magnet and coil were both held motionless, whether the magnet was within the coil or not, there was no current...Faraday hd thus discovered electricalinduction...It was to lead to great things, but this was not apparent.""(Asimov).""Although his discovery of the electric motor and the dynamo was almost entirely identical to his theoretical discoveries, it laid the foundation of the modern electrical industry - electric light and power, teælephony, wireless telegraphy, televison etc. - by providing for the production of continous mechanical motion from an electrical source, and vice versa."" (PMM, 308).Horblit, 29 - Milestones, 62. - Dibner, 64. - PMM, 308.‎

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‎"FARADAY, MICHAEL. - THE DISCOVERY OF ELECTRO-MAGNETIC INDUCTION (PMM 308) - GERMAN VERSION.‎

‎Experimental-Untersuchungen über Elektricität. (Frei übersetzt aus dem Philosop. Transact. f. 1832). (Erste-) Zweite Reihe. ( I-V). (I. Vertheilung elektrischer Ströme. II. Electricitätserregung durc Magnetismus. III. Neuer elektrischer Zustand der M...‎

‎Leipzig, Johann Ambrosius Barth, 1832. Contemp. hcalf., raised bands, gilt spine. Light wear along edges. In ""Annalen der Physik und Chemie. Hrsg. von J.C. Poggendorff"", Band 25. (Entire volume offered). VIII,648 pp. and 6 folded engraved plates. Small stamps on verso of titlepage and plates. Faraday's papers: pp. 91-142 a. pp. 142-186. with 3 folded engraved plates. Clean and fine.‎

‎First German editions of the 2 first memoirs of Faradays groundbreaking researches on electricity, constituting the first 2 papers of his ""Experimental Researches in Electricity"", and containing his fundamental discovery of electromagnetic induction, THE FOUNDATION OF NEARLY ALL THE ELECTRICITY IN USE TODAY. In 1820 Oersted had generated magnetism from electricity, Faraday here finds the opposite effect, generating electricity by magnetism. He also described the first electrical generator (second paper). THESE PAPERS ARE SOME OF THE GREAT CLASSICS OF CHEMISTRY AND PHYSICS.""Faraday demonstrated this theory involving the lines of force....by inserting a magnet into a coil of wire attached to a galvanometer. While the magnet was being inserted or removd, current flowed through the wire. If the magnet was held stationary and the coil moved over it one way or the other, there was current in the wire. In either case the magnetic lines of force about the magnet were cut by the wire.If the magnet and coil were both held motionless, whether the magnet was within the coil or not, there was no current...Faraday hd thus discovered electricalinduction...It was to lead to great things, but this was not apparent.""(Asimov).""Although his discovery of the electric motor and the dynamo was almost entirely identical to his theoretical discoveries, it laid the foundation of the modern electrical industry - electric light and power, teælephony, wireless telegraphy, televison etc. - by providing for the production of continous mechanical motion from an electrical source, and vice versa."" (PMM, 308).Horblit, 29 - Milestones, 62. - Dibner, 64. - PMM, 308.The volume contains further notable papers. Elie de Beaumont ""Zweiter geologischer Brief...an A.v. Humboldt über die relative Alter der Gebirgszüge"", pp. 1-58 a. 2 plates (one handcoloured), papers by Döbereiner, E. Lenz, Moser, Mitscherlich, de Saussure, J. Dumas, F.E. Neumann, Gay-Lussac, Johannes Müller ""Beobachtungen zur Analyse der Lymphe, des Bluts und des Chylus"", pp. 513-590.‎

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‎"HENRY, JOSEPH - THE DISCOVERY OF SELF-INDUCTION - GERMAN VERSION.‎

‎Ueber elektro-dynamische Induction.‎

‎(Leipzig, Johann Ambrosius Barth, 1842). Without wrappers. In ""Annalen der Physik und Chemie. Hrsg. von J.C. Poggendorff"", Ergänzungsband 1, Stück 2. Pp. 193-384 a. 1 folded engraved plate. (The entire issue offered). Henry's paper: pp. 282-312.‎

‎First German version of Henry's description of his discovery of self-induction. He missed the credit for the discovery of induction to Faraday, but he had done the key experiment ahead of Faraday, but Faraday was the first to publish. But he is credited for the discovery of self-induction (1832) and Faraday discovered it independently two years later (1834).""In Henry's paper, however, he explained thet the electric current in a coil can induce another current not only in another coil but in itself. The actual current observed in the coil is, then, the combination of the original current and the induced current. This is called self induction.""(Isac Asimov).The issue contains further notable papers Michael Faraday's ""Vierzehnte Reihe von Experimental-Untersuchungen über Elektricität"", 2o-22. (Nos 1667-1748). Pp. 249-281. First German version. In this paper FARADAYamplifies his theory of electrostatic induction by making further use of the analogy with the induction of magnetism. Whittaker describes the paper as having ""THE FUNDAMENTAL EQUATION OF ELECTROSTATICS"", as modified in order to take into account the effect of the specific inductive capacity.""(Whittaker I, pp.187-89).‎

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‎"JANSSEN, PIERRE JULES CÉSAR - THE DISCOVERY OF HELIUM IN THE SUN.‎

‎Éclipse de Soleil du 18 Aout 1868. Rapport adressé par M. Janssen au Maréchal de France Président du Bureau des Longitude.‎

‎Paris, G. Masson, 1878. 8vo. Contemp. hcalf, raised bands, gilt spine. Light wear along edges. Small stamps on verso of titlepage. In: ""Annales de Chimie et de Physique"", 4e Series - Tome 15. 512 pp. a. 3 folded engraved plates. (The entire volume offered). Janssen's memoir: pp. 414-426.‎

‎First appearance of this milestone paper in chemistry, physics and astronomy, announcing the discovery of the helium lines in the spectrum of the sun. It was Lockyer in the same year that named it 'helium' for Helios, the Greek God of the Sun. Helium was not discovered on the earth before 1895 by William Ramsay, and it was Crookes who established its identity with the helium Janssen and Lockyer observed in the spectrum of the sun.""He Janssen) met immortality by travelling to India in 1868 to study the total eclipse. It was then that he observed the helium line and forwarded the spectral data to ockyer. He also noted the size of the solar prominences. The day after the eclipse he attempted to take their spectra again and succeeded despite the absence of the obscuring moon. he then announced jubilantly that it was the day after the eclipse that was the real eclipse day for him. Lockyer also reported this method of studying prominences without an eclipse....Like Lockyer he lived to see his observation of the helium line vindicated by Ramsay's discovery of that element on earth.""(Asimov).""This (the discovery of helium lines in the sun by Lockyer) was announced on the same day by the French astronomer Janssen, who was in India observing a total eclipse. As a result, the French government some ten years later struck a medallion showing the heads of both scientists.By that time, the two men had made a much more dramatic discovery at the same time, this time in cooperation. Janssen, studying the spectrum ofthe sun during the eclipse, had noted a fine line he did not recognize. he send a report on this to Lockyer, an acknowledges expert on solar spectra. Lockyer compared the reported position of the line with lines of known elements, concluding that it must belong to a yeat unknown element, possibly not even existing on the earth. He named the element, from the Greek word for the sun.""(Asimov).Parkinson ""Breakthroughs"" 1868 A. - The volume contains other notable papers by Dumas, Berthelot et al.‎

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‎"RAMSAY, WILLIAM and MORRIS W. TRAVERS. - DISCOVERY OF THE ELEMENT KRYPTON.‎

‎On a new Constituent of Atmospheric Air. Received June 8 - Read June 9, 1898.‎

‎(London, Taylor and Francis, 1898) No wrappers. In ""Proceedings of the Royal Society of London."", Vol.63, Nos. 399-400 (both issues offered).. Pp. 373-480 a. 5 plates. Ransay & Travers' paper: pp. 405-408.‎

‎First appearance of the paper in which Ramsay and Travers announced their discovery of a new element which they named ""krypton"" (meaning hidden).""Dr. William Hampson presented them (Ransay & Travers) with about a liter of liquid air, which they used, not for liquefying the argon, but for obstaining sufficient skill in manipulation so that they would not risk loosing their precious fifteen liter of argon......The residue left after most of the liquid air had boliled away consisted largly of oxygen and nitrogen, which Ramsay and Travers temoved with red-hot copper and magnesium. ....(they) then examined the twenty-five cibic centimeters of residual gas, and when they found it to be inerst, they immediately placedit in a Pl'ucker tube connected to and induction coil and observed its spectrum. There was a bright yelælow line with a greener tint than that of the helium line and a brilliant green line that did nor coincide with any line of argon, helium, mercury, or hydrogen. They discoverede this gas on 30 May, 1898, and named it 'krypton'....they found that it belonged between bromine and rubidium in the periodic table, and so great was their excitement that the younger chemist almost forgot about his examination for doctor of sciwence which had been schedules for the next day.""(Weeks, p. 267).Parkinson ""Breakthroughs"", 1898 C.‎

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‎"(ARAGO, DOMINIQUE- FRANCOIS). - THE DISCOVERY OF MAGNETIZATION BY WAY OF THE VOLTAIC CURRENT.‎

‎Expériences relatives à l'aimantation du fer et de l'acier par l'action du courant voltaïque.‎

‎(Paris, Crochard, 1820). No wrappers as extracted fron 'Annales de Chimie et de Physique', Volume 15 (2e Series). Pp. 93-102.‎

‎First appearance of this importent paper in which Arago gives an account of his discovery of how iron and steel could be magnetized by the action of the voltaic current, THE FIRST STEP TOWARDS THE ELECTRIC TELEGRAPH. ""Arago .... made several important contributions to electromagnetism on his own. On 20 September 1820 he announced the discovery of the temporary magnetization of soft iron by an electric current, which suggested to Ampère a theory about the nature of magnetic ""currents"" and provided the technological key to the electric telegraph. Ampère calculated that the magnetic power could be multiplied by twisting the current-carrying wire into a helix, and with Arago he carried out the first experiments on primitive solenoids. In his historical articles Arago was always careful to credit Ampère with the major share of this discovery, which ultimately depended upon Ampère’s mathematical theory.""(DSB).Arago formed a close freinship with Fresnel,whose views on the nature of light he ardently supported. He assisted Fresnel in some of his most importent work and made original discoveries in the same field.Magie ""A Source Book in Physics"", p. 443 ff.‎

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‎"WURTZ, ADOLPHE. - THE DISCOVERY OF THE AMINES IN CHEMISTRY.‎

‎Mémoire sur une Série D'Alcaloïdes homologues avec L'Ammoniaque.‎

‎Paris, Victor Masson, 1855. 8vo. Without wrappers. In 'Annales de Chimie et de Physique', Series 3 , tome 30, December-issue. With halftitle to vol. 30. Pp. 385-508 a. 1 plate. (Entire issue offered). Wurtz's paper: pp. 443-506.‎

‎First appearance of the entire memoir in which Wurtz describes his outstanding discovery of Liebig’s prediction, that there might be organic compounds analogous to ammonia and derivable from it by the replacement of hydrogen - the amines. The discovery was announced in 1849, and a small extract was printed in ""Comptes rendu"" (4 pp.). The offered paper is the memoir in full.Wurtz is most noted for his investigation of glycols and for his discovery of the amines. The latter discovery in 1849 (the paper offered) was very significant at the time, for ot suggested the possibility of a new type, the ammonia type, which helped to explain the behaviour of nitrogenous compounds. (Leicester & Klickstein ""A Source Book.."", pp. 362-63). - Parkinson ""Breakthroughs"" 1849 C.Charles Adolphe Wurtz, was born at Strasbourg 1817. For many years he was Professor of Chemistry at the Ecole de Médicine and at Sorbonne in Paris. He was known not only for his researches in organic chemistry but also for his many literary works. He was editor of a Dictionnaire de Chemie Pure et Appliquée, and after 1868 one of the editors of the Annalen der Chemie et de Physique. He died in Paris in 1884.‎

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‎"RUNGE, F.F. - THE DISCOVERY OF PHENOL.‎

‎Ueber einige Produkte der Steinkohlendestillation.‎

‎(Leipzig, Johann Ambrosius Barth, 1834). Without wrappers. Extracted from ""Annalen der Physik und Chemie. Hrsg.von Poggendorff"", Bd. 31, No 5. Pp. 65-80.‎

‎First printing of the paper in which Runge discloses his discovery of carbolic acid or phenol, and how he prepared it by distilling coal.Parkinson ""Breakthroughs"", 1834 C. - Partington IV, pp. 183-84.‎

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‎"MÜLLER, JOHANNES & THEODOR SCHWANN. - THE DISCOVERY OF PEPSIN, THE FIRST KNOWN ANIMAL ENZYME & THE ""FIBRES OF REMAK""‎

‎Versuche über die künstliche Verdauung des geronnenen Eiweisses (Müller & Schwann) (+) Ueber das Wesen des Verdauungsprocesses (Schwann). 2 paers.‎

‎Berlin, G. Eichler, 1836. In ""Archiv für Anatomie, Physiologie und Wissenschaftliches Medicin Herausgegeben von Johannes Müller"". Jahrgang 1836. Pp. 66-89 a. pp. 90-139. The entire volume offered in its 6 parts (in 5), all 5 issues uncut with orig. printed warppers. (2),CCXXIV,390 pp. and 15 engraved plates. The 2 first issues with a faint dampstain to lower part of leaves and plates.‎

‎First appearance of an importent paper in the history of biology, in which Schwann describes his discovery and isolation of pepsin, the substance in the stomach that aids digestion of eggwhite. It is the FIRST KNOWN ANIMAL ENZYME. The paper appeared at the same time in ""Annalen der Physik und Chemie. Hrsg. von J.C. Poggendorff"".Theodor Schwann (1810-1882) was a great German physiologist, pathologist, and experimenter. One of the founders of the cell doctrine and of the idea of the living nature of yeast. Born at Neuss, near Düsseldorff. A catholic, educated in the Jesuit Gymnasium in Cologne. Intended for the church but took to medicine. He was a pupil of Johannes Müller and a collegueand lifelong friend of J. Henle, the anatomist. In Berlin Schwann was Johannes Müller's assistent for five years, and it was then that he discovered pepsin in 1836 (the paper offered).Parkinson ""Breakthroughs"" 1836 B. - Garrison & Morton no. 991.The first paper offered, written together with Johannes Müller records the preliminary investigaions leading to the discovery of Pepsin. - Garrison & Morton no. 990.The volume also contains another famous paper by ROBERT REMAK ""Vorläufige Mittheilung microscopischer Beobachtungen über den innern Bau der Cerebrospinalnerven und über die Entwicklung ihrer Formenelemente. (Hierzu Tafel IV). Pp. 145-161. This paper contains the first announcement of his DISCOVERY OF ""FIBRES OF REMAK"", the non-medullated nerve-fibres. (Garrison & Morton no. 1260.‎

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‎"STEENSTRUP, JOHANNES JAPETUS SMITH. - THE DISCOVERY OF ""ALTERNATION OF GENERATIONS''.‎

‎Om Forplantning og Udvikling gjennem vexlende Generationsrækker, en særegen Form for Opfostringen i de lavere Dyrklasser. [On Reproduction and Development through Alternation of Generations, a Special Form of Propagation in Lower Animals]. (+)Undersög...‎

‎Kjöbenhavn, Bianco Luno, 1842 a. 1845. 4to. Bound in one contemp. halfcalf, spine gilt. A small tear to backhinge at lower compartment of spine. IV,76 pp. and 3 double-page, folded lithographed plates with many figs. + XIV,88 pp. and 2 double-apge lithographed plates with many figs. Light browning to the last leaves of the second work.‎

‎The scarce first edition of the work in which Steenstrup describes his discovery of the principle of 'ALTERNATION OF GENERATIONS'', sexual and asexual in plants and animals. ""(Steenstrup) showed that certain animals produce offspring which never resemble them but which, on the other hand, bring forth progeny which return in form and nature to their grandparents or more distant ancestors."" (Garrison & Morton No 217). A German translation was published the same year, and an English in 1845. Norman 2009 (German translation). ""The second major publication - (the first dealing with geology) - of 1842 was ""Om Forplantning og Udvikling gjennem vexlende Generationsrækker..."", (the work offered), Steenstrup's comprehensive presentation of the form of reproduction that he called 'alternation of generations', that is, the alternation of asexual and sexual reproduction, or metagenesis. This phenomenon had previously been described by Chamisso, but Steenstrup included a greater number of observations, based on a significantly wider range of subjects, and provided an importent chapter on its meaning. Steenstrup's growing reputation, won him an appointment as professor of zoology at the University of Copenhagen, where he tought from 1846 until 1885.""(DSB XII, p. 9).‎

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‎ROBIQUET, (PIERRE JEAN) - THE DISCOVERY OF THE FIRST AMINO ACID.‎

‎Essai analytique des asperges"‎

‎Paris, Chez Bernard, AN XIII (1805). No wrappers. In: ""Annales de Chimie ou Recueil de Mémoires.."" Vol. 55, Cahier 2 (30 Thermidor an XIII). Pp. 113-224 (entire issue offered). Htitle to vol. 55 present. Robiquet's paper: pp. 152-171.‎

‎First appearance of Robiquet's first chemical paper, in which he relates his discovery of asparagine by analysis of asparagus juice, the first amino acid to be discovered. The following year he made the first isolation of this amino acid together with Vaguelin. Pierre Jean Robiquet was a French chemist, who laid founding work in identifying amino acids, the fundamental bricks of proteins, through recognizing the first of them, asparagin, in 1806, in the take up of the industry of industrial dyes, with the identification of alizarin in 1826, and in the emergence of modern medications, through the identification of codeine in 1832, a powerful molecule today of widespread use with analgesic and antidiarrheal properties.‎

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‎PROUST, (JOSEPH LOUIS) - THE DISCOVERY AND ISOLATION OF GRAPE-SUGAR.‎

‎Memoire sur le Sucre de raisin" (+) Suite du Mémoire....sur le sucre de raisin. (2 Parts).‎

‎Paris, Chez Bernard, 1806. No wrappers. Ectracts from ""Annales de Chimie ou Recueil de Mémoires.."" Vol. 57. Pp. 131-174 a. pp. 225-272. With the titlepage to volume 57.‎

‎First appearance of a classic paper in which Proust describes his discovery of Grape.Sugar and the identificationof this with glucose. He investigated the varieties of sugar that occur in sweet vegetable juices, distinguishing three kinds, and he showed that the sugar in grapes, of which he announced the existence to his classes at Madrid, is identical with that obtained from honey by the Russian chemist J. T. Lowitz.Proust is famous for his work on the steadiness of composition of chemical compounds.""In chemistry, the law of definite proportions, sometimes called Proust's Law, states that a chemical compound always contains exactly the same proportion of elements by mass. An equivalent statement is the law of constant composition, which states that all samples of a given chemical compound have the same elemental composition. For example, oxygen makes up 8/9 of the mass of any sample of pure water, while hydrogen makes up the remaining 1/9 of the mass. Along with the law of multiple proportions, the law of definite proportions forms the basis of stoichiometry.""(Wikipedia).‎

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‎"DAVY, HUMPHREY. - THE DISCOVERY OF CHLORINE DIOXYD.‎

‎Some experiments on a solid compound of iodine and oxygene, and on its chemical agencies. Read April 20, 1815. (+) On the action of acids on the salts usually called hyperoxymuriates. Read May 4, 1815. (2 papers).‎

‎(London, W. Bulmer and Co., 1815). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1815 - Part II. Pp. 203-213 a. pp. 214-219.‎

‎First appearance of two importent papers by davy. In the second paper offered, he relates his discovery of chlorine dioxyd.""By explosion over mercury he found that 2 vols. give from 2.7 to 2.9 of gas, and this would probably be 3 vols. if no chlorine had been absorbed by the mercury. This gas contains 2 vols. of oxygen and the remainder chlorine, hence the compound consists of 'two in volume of oxygen and one of chlorine, condensed into the space of two volumes' (ClO2). He found it to explode at about 100 deg. with more viollence than euchlorine.""(Partington III, p. 57).Together with ROBERT PORRETT ""Further analytical experiments relative to the constitution of the prussic" of the ferruretted chyazic, and of the sulphuretted chyazic acids and of their salts" together with the application of the atomic theory to the analysis of these bodies."", pp. 220-230 a. 2 tables, one folding.‎

Referencia librero : 45715

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‎DAVY, HUMPHRY - THE DISCOVERY OF POTASSIUM AND SODIUM.‎

‎The Bakerian Lecture, on some new Phenomena of chemical Changes produced by Electricity,particularly the Decomposition of the fixed Alkalies, and the Exhibition of the new substances which constitute their bases" and on the general Nature of alkaline ...‎

‎(London, W. Bulmer and Co., 1808). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1808 - Part I. Pp. 1-44. Clean and fine, wide-margined.‎

‎First printing of this importent historical paper in chemistry, in which Davy shows that electricity is capable of decomposing some alkalies, isolating two new substances and discovering potassium and sodium. Neville in his Historical Chemical Library vol. I, p.340, writes about this paper ""ONE OF THE GREAT CLASSIC RESEARCHES IN CHEMISTRY, in which Davy announced in this, his second Bakterian lecture, the isloation of metallic potassium and sodium by the electrolytic decomposition of their fused oxides.""""He (Davy) began his own electrical experiments...The results were spectacular. On October 6, 1807, the current passing through molten potash liberated a metal, which Davy called potassium. The little globules of shining metal tore the water molecule apart as it eagerly recombined with oxygen and the liberated hydrogen burst into lavender flame. Davy danced about in a delirium of joy. A week later he isolated sodium from soda.""(Asimow). The paper offered here describes these discoveries.""Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation, but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile, interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle, who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800, and his numerous discoveries were presented in his Bakerian lecture to the Royal Society on November 20, 1806.(A Source Book in Chemistry p. 243). - Wheeler Gift: 2514.‎

Referencia librero : 45884

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[Libros de Herman H. J. Lynge & Son]

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‎"DAVY, HUMPHRY - THE DISCOVERY OF HYDROGEN TELLURIDE.‎

‎The Bakerian Lecture for 1809. On some new Electrochemical Researches, on various Objects, particularly the metallic Bodies, from the Alkalies, and Earth, and on some Combinations of Hydrogene. Read November 16, 1809.‎

‎(London, W. Bulmer and Co., 1810). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1810 - Part I. Pp. 16-74 and 2 engraved plates showing Davy's electrochemical apparatus for decomposing substances, Davy's versions of the Voltaic-pile.. Plates a bit brownspotted, otherwise clean and fine, wide-margined.‎

‎First appearence of this historical chemical paper, Davy' fifth Bakerian Lecture, in which he announced his discovery of hydrogen telluride.""Mr. Davy having from the commencement of his electro-chemical researches, communicated the several steps of his progress to the Society (The Royal Society), takes the present opportunity of reporting the results of his further inquiries under four principal heads. First, on the nature of the metals of the fixed alkalis. Second, on the nature of Hydrogen and composition of ammonia. Thirdly, on the metals of the earth"" and Fourthly he makes a comparison between the antiphlogistic doctrine, and a modified phlogistic hypothesis.""(Abstract). He further gives arguments for considering potassium and sodium, which he discovered in 1808, as a element.""Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation, but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile, interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle, who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800, and his numerous discoveries were presented in his Bakerian lectures."" - Wheeler Gift: 2518.Also with William Hyde Wollaston ""The Croonian Lecture. Read November 16, 1809.(On Muscular Action - On Sea-Sickness - On the salutary Effects of Riding, and other Modes of Gestation). Pp. 1-15.‎

Referencia librero : 45887

Livre Rare Book

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‎"CASSINI, J. - DISCOVERY OF THE INCLINATION OF A SATELITTE.‎

‎Nouvelles Decouvertes sur les Mouvements des Satellites de Saturne.‎

‎(Paris, L'Imprimerie Royale, 1717). 4to. Without wrappers. Extracted from ""Mémoires de l'Academie des Sciences. Année 1714"". Pp.361-378 and 1 folded engraved plate.‎

‎First printing of the paper in which Cassini describes his discovery of the inclination of the orbit of Saturn's fifth satellite.‎

Referencia librero : 45962

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‎"ØRSTED (OERSTED), H.C. - THE DISCOVERY OF ELECTROMAGNETISM - FIRST ANNOUNCEMENT IN FRENCH.‎

‎Experimenta circa Effectum, etc. Expériences sur l'effet du conflict électrique sur l'aiguille animantée.‎

‎(Paris, Crochard, 1820). No wrappers. In ""Annales"". In ""Annales de Chimie et de Physique, Par MM. Gay-Lussac et Arago"" Tome XIV, Cahier 4, Titlepage to vol. 14 + pp. 337-442. (Entire issue offered). Ørsted's paper: pp. 417-25. A few scattered brownspots.‎

‎First French translation and the first translation of Oersted's epoch-making announcement in his Latin pamphlet ""Extperimenta circa effectum conflictus electrici in acun magneticam. Hafniæ, 1820"" (privately printed in a very small number, and only distributed to colleques in Europe). This discovery and confirmation of the connection between 2 forces, electricity and magnetism, must be considered one of the happiest events in the history of science, both with regard to scientific and practical results. - ""From the moment that Ørsted's discovery became known it created an enormous sensation. The results communicated were so astounding that they were received with a certain distrust, but they were stated with such accuracy that it could hardly be permitted to entertain any doubts. In the course of a short time the treatise was translated into all the chief languages."" (Kirstine Meyer). - Dibner:61 - PMM: 282 - Horblitt: 3 b. - Sparrow: 152.‎

Referencia librero : 46026

Livre Rare Book

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‎"UNVERDORBEN, OTTO. - THE DISCOVERY OF ANILINE.‎

‎Ueber das Verhalten der organischen Körper in höheren Temperaturen.‎

‎Leipzig, Johann Ambrosius Barth, 1826. Contemp. hcalf. Gilt spine. A few scratches to spine. In ""Annalen der Physik und Chemie. Hrsg.von Poggendorff"", Bd. 8. (10),526 pp. and 3 folded engraved plates. Small stamps onverso of titlepage. (Entire volume offered). Unverdorben's paper: pp. 253-265, 397-410, 477-487. Clean and fine.‎

‎First appearance of the paper in which Unverdorben describes the method by which he discovered Aniline, which became so importent in the manufacture of dyes, plastics, and pharmaceuticals. ""Aniline (from the Portugese anil, applied to indigo, and derived from the Arabic an-nil, the blue substance), was first obtained by Unverdorben by heating indigo, and was given the name 'crystalline'. In 1841 Carl Julius von Fritzsche (1807-71), an assistant to Mitscherlich and, later, a member of the Academy of Sciences in St. petersburg, obtained the same compound from anthranilic acid, which was produced by the action of caustioc alkalis on indigo, and called it 'aniline'... in 1843 Hofmann showed that the three substances, crystalline, aniline and benzidam, were identical with the base isolated from coal tar.""(Findlay ""A Hundred years of Chemistry"", p. 134).Parkinson ""Breakthroughs"" 1826 C.The volume contains other importent papers Antoine Jerome Balard ""Ueber eine besondere Substanz im Meereswasser"" in which he describes his discovery of the element BROMINE, first German edition, pp. 114-124 a. pp. 319-336. (Parkinson ""Breakthroughs"" 1826 C.). And Eilhard Mitscherlich ""Ueber eine neue Klasse von Krystallformen"", pp. 427-442.‎

Referencia librero : 46031

Livre Rare Book

Herman H. J. Lynge & Son
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[Libros de Herman H. J. Lynge & Son]

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‎"DAVY, HUMPHRY - THE DISCOVERY OF HYDROGEN TELLURIDE - THE RIVALRY WITH GAY-LUSSAC & THENARD.‎

‎Nouvelles Recherches électro-chimiques, principalement relatives aux substances métalliques tirées des alcalis et de terres, et à quelques combinations de l'Hydrogène. (+) Suite des Recherches... (+) Sur les Observations sur les Recherches faites p...‎

‎Paris, J. Klostermann, 1810. Contemp. hcalf. Spine gilt. Slightly rubbed. A few scratches to binding. Small stamps on verso of titlepage.In: ""Annales de Chimie, ou Recueil de Mémoires concernant la Chemie"" Tome 75. 336 pp. a. 2 folded engraved plates. Some scattered brownspots. The papers: pp. 27-77, 129-175, 256-263, 264-273, 274-289 a. 290-316.‎

‎First French version of Davy's ""The Bakerian Lecture for 1809. On some new Electrochemical Researches, on various Objects, particularly the metallic Bodies, from the Alkalies, and Earth, and on some Combinations of Hydrogene. Read November 16, 1809."", together with the controversy papers by Davy and Gay-Lussac & Thenard.""Mr. Davy having from the commencement of his electro-chemical researches, communicated the several steps of his progress to the Society (The Royal Society), takes the present opportunity of reporting the results of his further inquiries under four principal heads. First, on the nature of the metals of the fixed alkalis. Second, on the nature of Hydrogen and composition of ammonia. Thirdly, on the metals of the earth"" and Fourthly he makes a comparison between the antiphlogistic doctrine, and a modified phlogistic hypothesis.""(Abstract). He further gives arguments for considering potassium and sodium, which he discovered in 1808, as a element.""""Gay-Lussac had a slight rivalry between himself and the creation scientist Sir Humphry Davy. Davy was chemically preparing Potassium and Sodium through an electrical current, and this made Gay-Lussac and Thénard envious of his success. They too decided to perform the same task, but they had no battery at their disposal as Davy had, so they had to form another way to chemically prepare the two elements. In 1808, they used a red-hot iron fused to potash, the water-soluble form of a manufactured salt containing potassium, to perform this task, a method that Davy admitted had its advantageous qualities. Gay-Lussac and Thénard were successful in preparing Potassium, and continued to make a full analysis of its chemical properties, and began to use it for their own experiments. In 1809, Davy performed the same task, using it to reduce Boron in Boracic acid.""‎

Referencia librero : 46377

Livre Rare Book

Herman H. J. Lynge & Son
Copenhagen Denmark Dinamarca Dinamarca Danemark
[Libros de Herman H. J. Lynge & Son]

€335.75 Comprar

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