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‎"THOMSEN, JULIUS.‎

‎Thermochemiske Undersøgelser over Affinitetsforholdene imellem Syrer og Baser i vandig Opløsning. I-XII (in 7 parts, all)‎

‎Kjøbenhavn, Bianco Luno, 1869-73. 4to. Bound in one contemp. hcloth. Around 300 pp., plates. Some brownspots.‎

‎First edition of Thomsens main contributions in thermochemistry, undoubtly the most importent contribution from a Dane in chemistry in the 19th century. - The construction of a complete and quantitative system of thermochemistry required an extensive and accurate collection of thermochemical data over and above the observations upon which the principle was based. The amount of data which he amassed was so great that it enabled him the calculation of heats of reaction for practically speaking every fairly common inorganic reaction. The results, which are based between three and four thousand measurements, were later collected in his famous work ""Thermochemische Untersuchungen"" (The Danish original oferred here).‎

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‎JØRGENSEN, S.M.‎

‎Det kemiske Syrebegrebs Udviklingshistorie indtil 1830. Efterladt Manuskript udgivet af Ove Jørgensen og S.P.L. Sørensen.‎

‎København, Høst, 1916. 4to. Orig. bogtrykte omslag. 109 pp.‎

‎(Videnskabernes Selskabs Skrifter).‎

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‎"WOULFE, PETER.‎

‎Experiments on some Mineral Substances. Communicated at the Desire of William Hunter. Read Nov. 19, 1778.‎

‎(London, J. Nicols, 1779). 4to. Extract from ""Philosophical Transactions, of the Royal Society of London."" Vol. 69, Year 1779 - Part I. Pp. 11-34.‎

‎First printing. In the paper Woulfe described a white tin ore and other minerals. (Partington III: p. 301).Woulfe is mainly remembered for the two-necked bottle generally known as a Woulfe’s bottle which has long been a standard item of equipment in most chemical laboratories. The apparatus has been traced back to J. R. Glauber, and its attribution to Woulfe seems to stem from his use of a vessel with two outlets in a series of distillation experiments described in 1767. His ""new method"" was designed to prevent the escape of fumes ""very hurtful to the lungs"" by passing them through a tube into water.(DSB).‎

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‎"DUFAY (DU FAY), CHARLES FRANCOIS DE CISTERNAY. - PHOSPHORESCENCE.‎

‎Mémoire sur un grand Nombre de Phosphores nouveaux.‎

‎(Paris, L'Imprimerie Royale, 1732). 4to. Without wrappers. Extracted from ""Mémoires de l'Academie des Sciences. Année 1730"". Pp. 524-535.‎

‎First appearance of Dufay's importent work on phosphorescence.""Chemists had long been acquainted with a fes minerals like the Bologna stone (BaS) and Balduin's hermetic phosphor (plain CaS) that glowed after exposure to light. Greatmystery surrunded those expensive and supposedly rare substances. Dufay detested mysteries and held as a guiding principle that a given physical property, however bizarre, must be assumed characteristic of a large class of bodies, not of isolated species. He found that almost everything except metals and very hard gems could be made phosphorescent: he depressed the phosphor market by describing his procedure: and he became sensitive to the endless small variations in the physical properties of bodies. 'How many things behave that seemed similar, and how many varieties there are in effects that seemed identical."" (Heilbron ""Electricity in the 17 & 18 Centuries"", p. 251).Another paper attached to Dufay's paper is Charles Pitot ""Reflexions sur le Mouvement des Eaux"". Pp. 536-544 a. 1 folded engraved plate. (Poggendorff II:p. 459).Partington ""A History of Chemistry"" III, p.66‎

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‎"DUFAY (DU FAY), CHARLES FRANCOIS DE CISTERNAY.‎

‎Memoire sur les Barometres lumineux.‎

‎(Paris, L'Imprimerie Royale, 1725). 4to. Without wrappers. Extracted from ""Mémoires de l'Academie des Sciences. Année 1723"". Pp. 295-306.‎

‎First appearance of Dufay's first work. ""His first academic paper (1723), on the mercurial phosphorus, already displayed the characteristics which distinguished his later work: full command of earlier writings, clear prescriptions for producing the phenomena under study, general rules or regularities of their action, thorough study of possible complications or exceptions, and cautious mechanical explanations of a Cartesian flavor. This ""phosphor"" - the light sometimes visible in the Torricelli space when a barometer is jostled - much perplexed the physicists of the era, primarily because it did not always occur under apparently identical conditions. Dufay found that traces of air or water vapor occasioned the failures, which could be entirely eliminated with a technique of purification taught him by a German glassmaker. He explained the light in terms of Cartesian subtle matter squeezed from the agitated mercury"" although he knew the work of Francis Hauksbee (the elder), he suggested no connection with electricity.""(DSB).‎

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‎"ARAGO, FRANCOIS - LOUIS DAGUERRE. - THE INVENTION OF THE DAGUERREOTYPE.‎

‎Fixation des images qui se forment au foyer d'une chambre obscure. (Seance du Lundi 7 Janvier 1839). (+) Le Daguerréotype. (Seance du Lundi 19 Aout 1839).‎

‎Paris, Bachelier, 1839. 4to. No wrappers. In: ""Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences"", Tome VIII (No.1)+ IX, (No. 8) Entire issues offered with htitles and titlepages to both volumes. Pp. 1-36 + Pp. 249-282 and 1 lithographed plate. The papers: pp. 4-7 and pp. 250-267. A faint stamp to top of titlepages. A few brownspots to titlepages.‎

‎First Edition of the official and complete report of the invention of the ""daguerreotype"", the photographic process invented by Louis Daguerre. Together with the preliminary report of the invention (OF JANUARY 7). The presentation by Arago preceeded Daguerre's own publication ""Historique de description des procédés du daguerreotype et du diorama"", (1839). ""When the attempt to exploit the process of daguerreotype was unsuccessfull, Daguerre and Nièpce decided to offer their method to the government. Daguerre approached Francois Jean Arago, to whom he imparted, under the seal of secrecy his processes and those of Nicéphore Niépce. It was fortunate that Arago possessed such a great insight into the invention, which he received enthusiastically. He reported the invention of the daguerretype to the Academy of Sciences on January 7, 1839. The secrecy, however, was not observed very carefully, for the ""Gazette de France"" published a note abouit it on January 6, 1839, although without printing any details.""(Eder ""History of Photography"").‎

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‎"DAGUERRE, LOUIS. - THE HELIOGRAPHIC PROCESS.‎

‎Des procédés photogéniques considérés comme moyens de gravure. - Lettre de M. Daguerre à M. Arago. (Séance du undi 30 Septembre 1839).‎

‎(Paris, Bachelier, 1839). 4to. No wrappers. In: ""Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences"", Tome IX, No 14). Entire issue offered. Pp. 415-436. Daguerre's letter: pp. 423-429.‎

‎First printing of Daguerres letter to Arago in which he relates the process of heliography and describes his contract with Niépce to exploit the heliogrphis process. The Heliogravure was invented by Niépce.‎

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‎"KAPITZA, P (+) J. F. ALLEN (+) A. D. MISENER.‎

‎Viscosity of liquid Helium below the lambda-point [Kapitza] (+) Flow of liquid Helium II [J. F. Allen & A. D. Misener] [The volume also contain the following papers: New phenomena connected with heat flow in liquid Helium II [J. F. Allen & H. Jones] (... - [THE DISCOVERY OF SUPERFLUIDITY]‎

‎New York, Macmillian and Co, 1938. Royal8vo. In publisher's pictorial cloth with the original wrappers [in the back]. Gilt lettering and Nature's logo to spine and front board. Entire issue of ""Nature"", January - June, 1938, Vol. 141. ""Emmanuel College"" in gilt lettering to spine and two library stamps to title-page and first index page. Two small white paper labels pasted on to spine and a small tear to top of spine. Very slight wear to extremities, otherwise a very fine and clean copy. Rare in the publisher's binding. P. 74"" P. 75. [Entire volume: LXIV, 1156 + VIII, IV, VIII, VIII, XVI, VIII, VIII, XVI, VIII, XII, VIII, XII, XII, IV, IV, VIII, XII, VIII, VIII, VIII, VIII, XII, VIII, IV, XVI, CCLX (Advertisements).‎

‎First publication of these two seminal papers which constitutes one of the most significant discovery in 20th century physics. It ushered a golden period of low-temperature physics and created a new research field within physics which was later to be called quantum liquids. Both paper described a hitherto unknown state of matter: superfluidity of matter. The two discoveries were made independently, Kapitza's paper superseding Allen and Misener's by two weeks. Both studies reported that liquid helium flowed with almost no measurable viscosity below the transition temperature of 2.18 K.""Although the discovery of superfluidity stands as one of the most significant in physics in the 20th century, it was to be 40 years before the Royal Swedish Academy of Sciences honoured this seminal discovery with a Nobel prize - an exceptionally long interval. In 1978 Kapitza, by then 84, was given half of that year's Nobel Prize for Physics with a somewhat vague citation reading ""for his basic inventions and discoveries in the area of low-temperature physics"". The other half did not go to Allen and Misener. Today, science popularizers generally give sole credit for the discovery of superfluidity to Kapitza."" (Physics world, University of Toronto.). ""Kapitza observed that He II flowed between two closely spaced parallel plates extremely rapidly compared to He I, for the same pressure difference. This result, published in Nature on 8 January 1938, showed unambiguously that here was a new and mysterious kind of liquid - one with almost no viscosity. On the page facing Kapitza's one-page paper was another by the young Canadian physicists Jack Allen and Donald Misener, with essentially equivalent results on helium flow on long capillary tubes. It was submitted two weeks after Kapitza's, but both papers are the standard reference for the discovery of superfluidity"". (Griffin, A Century of Nature, 2003, p. 52).While investigating the thermal conductivity of liquid helium, Kapitsa measured the flow as the fluid flows through a gap between two discs into a surrounding bath. Above the lambda point, there was little flow, but below the lambda temperature, the liquid flowed with such great ease that Kapitsa drew an analogy with superconductors. It was a liquid of zero viscosity. He discovered the phenomenon in 1937 and published a paper about it in Nature in January 1938. He wrote: ""The helium below the lambda point enters a special state that might be called a ‘superfluid.’"" (DSB).Today the theory behind superfluidity is widely used within a broad variety of different subject such as spectroscopic and in high-precision devices as gyroscopes which allow the measurement of some theoretically predicted gravitational effects. In 1999, a type of superfluid was used to trap light and greatly reduce its speed. Light was passed through a Bose-Einstein condensed gas of sodium (superfluid) and found to be slowed to 17 m/s from its normal speed of 299,792,458 metres per second.Brandt, The Harvest of a Century, Pp. 254-7.‎

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‎"DRAPER, (JOHN) WILLIAM. - THE FIRST DAGUERREOTYPE PORTRAIT.‎

‎On the Process of Daguerreotype, and its application to taking Portraits from the Life.‎

‎London, Richard and John Taylor, 1840. Contemp. hcalf. A nic to spine at upper hinge. Hinges weakening (not loose). Gilt lettering to spine ""Philosophical Magazine"" - Vol.XVII. In: ""The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. Conducted by David Brewster et al."". Vol. XVII. A stamp to titlepage and a few other pages. Entire volume offered. VIII,552 pp. Draper'spaper: pp. 217-225.‎

‎First printing of the famous paper in which Draper relates how he was able to made the first photographic portrait on a daguerreotype plate, giving an ennormously long exposure. The subject of the portrait, Draper's assistant, powdered his face with flour and sat in front of the camera for a half hour facing the sunlight.Draper stated that it is possible to make portraits in full sunlight, using mirrors as light reflectors. ""But in the reflected sunshine, the eye cannot support the effulgence of the rays. It is therefore necessary to pass them through some blue medium, which shall abstract from them their heat and take away their offensive brilliancy. Ihave used for this purpose blue glass, and also ammoniaco-sulphate of copper, contained in a large trough of plate glass, the interstice being about an inch thick."" (p. 217 in the paper offerd).""Draper first achieved wide celebrity for his pioneering work in photography. As early as 1837, while still in Virginia, he had followed the example of Wedgwood and Davy in making temporary copies of objects by the action of light on sensitized surfaces. When the details of Daguerre’s process for fixing camera images were published in various New York newspapers on 20 September 1839, Draper was ready for the greatest remaining challenge, to take a photographic portrait. A New York mechanic, Alexander S. Wolcott, apparently won the race by 7 October. But if Draper knew of this, he persisted in his own experiments and succeeded in taking a portrait not later than December 1839. His communication to the Philosophical Magazine, dated 31 March 1840, was the first report received in Europe of any photographer’s success in portraiture. The superb likeness of his sister Dorothy Catharine, taken not later than July 1840, with an exposure of sixty-five seconds, seems to be the oldest surviving photographic portrait.""(DSB).The volume contains also Michael Faraday's importent letter to Gay-Lussac on induction in the first English version. ""On Magneto-electric induction."", pp. 281-89 a. pp.356-366. (Originally published in French in ""Annales de Chimie et Physique"" in 1832.‎

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‎"(PROUT, WILLIAM). - ""PRIMA MATERIA"" FOUND - PROUT'S HYPOTHESIS.‎

‎On the Relation between the Specific Gravities of Bodies in their Gaseous State and the Weight of their Atoms. (+) Correction of a Mistake in the Essay on the Relation between the Specific Gravities of Bodies in their Gaseous State and the Weights of ...‎

‎London, Baldwin, Cradock, and Joy, 1815 a. 1816. 8vo. Bound in 2 ciontemp. full moiré cloth, rebacked. Endpapers renewed. Spine gilt and with gilt lettering. In: ""Annals of Philosophy...by Thomas Thomson"", Vol. VI, July to December, 1815 and Vol. VII January-June 1816. VIII,480 pp. a. 6 plates + VIII,488 pp. a. 10 plates. Some brownspots to plates and offsettings from plates, not affecting Prout's papers. Prout's papers: pp. 320-330 a. pp. 111-113. Internally clean.‎

‎First appearance of a milestone-paper in the history of chemistry and atomic theory as Prout here set forth - coupled with experimental evidences - the theory that the elements seems to have atomic weights that are whole number multiples of the atomic weight of hydrogen and that all elements is in some way a combination of hydrogen atoms. The theory announced here in Prout's first paper on the subjecy, is called PROUT'S HYPOTHESIS, and it was ""not until the twentieth century that new views of the atom, arising out of the Second Scientific revolution of the 1890s, revitalized the notion. As a result of the work of Soddy and Aston a new form of Prout's hypothesis was established and Prout was found to be not wrong, but merely a century premature.""(Asimov).""The concept of a primary substance as the basis of all matter has a tempting simplicity which has appealed to thinkers from the classic Greek age to our own day. The idea was revived in a new garb in 1815-1816 by a London physician, Willia Prout, who observed that with few exceptions the specific gravities of elementary gases (i.e., their atomic weight) were evenmultiples of of that of hydrogen. The experimental errors in the data then available were such asto make the hypothesis appear plausible. Prout concluded, therefore, that hydrogen isthe fundamental constituent from which all other elements are compounded....... his idea that all matter is composed of the same material is now established.""(Leicester & Klickstein in ""A Source Book in Chemistry 1400-1900"", p. 275 ff.). - See also note to PMM 407, entry Moseley The Atomic Table.Parkinson ""Breakthroughs"", 1816 C.‎

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‎"BERZELIUS, JÖNS JACOB. - THE INTERNATIONAL LANGUAGE OF CHEMISTRY INTRODUCED.‎

‎Experiments on the Nature of Azote, of Hydrogen, and of Ammonia, and upon the Degrees of Oxidation of which Azote is susceptible. (+) Essay on the Cause of Chemical Proportions, and on some Circumstances relating to them: together with a short and eas...‎

‎London, Robert Baldwin, 1813 a. 1814. 8vo. 2 contemp. hcalf. Marbled boards. Spines lacks and boards detached. In: ""Annals of Philosophy"" or Magazine of Chemistry, Mineralogy, Mechanics... By Thomas Thomson"". Vol. II and Vol. III. Entire volumes offered. Berzelius' papers: pp. 276-284, 357-368 (the first paper in vol. II), pp. 443-454 (vol. II) a. pp. 51-62, 93-106, 244-257 a. 353-364. (vol. III). Internally fine and clean.‎

‎First printing of these milestone papers in the history of chemistry, where Berzelius introduced his famous chemical symbolism whereby an element is generally represented by the first letter of its Latin name, or, in the event of elements having the same first letter, by the first two letters. Even though his atomic symbols were introduced in 1813 (see the note on p. 359 in the first paper), it was quite a few years before Berzelius's symbols were adopted by the chemistry community. But once accepted, they became the new international language of chemistry.Berzelius ""contributed more to the development of the atomic theory and to the setting up of accurate values of the atomic weights than did any other worker of the time. Of his contributions, moreover, to the development of the atomic theory and the advancement of chemical science, not the least valuable was the introduction of a chemical symbolism which, with slight modification, is in use at the present day. By giving his symbols a quantitative meaning - the symbol of an element representing one atomic proportion by weight - it was possible ""to show briefly and clearly the number of elementary atoms in each compound and, after the determination of their relative weights, present the results of each analysis in a simple and easely retained manner"". This symbolism was speedily adopted on the Continent but, in England, only after some considerable time.""(Findlay ""A Hundred Years of Chemistry"", p. 14.).Parkinson ""Breakthroughs"", 1813 C. - Leicester & Klickstein ""A Source Book in Chemistry"", p. 258 ff. - Holmberg 1813:28 a. The volume contains other notable papers THOMAS THOMSON ""On the Discovery of the Atomic Theory"", pp. 329-338. and JOHN DALTON ""Remarks on the Essay of Dr. Berzelius on the Cause of Chemical Proportions"", pp. 174-180 (Vol. III).‎

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‎"CAILLETET, L. - RAOUL PICTET - THE LIQUEFACTION OF OXYGEN A BREAKTHROUGH IN LOW-TEMPERATURE CHEMISTRY.‎

‎De la Condensation de l'oxygè et de l'oxyde de carbone. (Cailletet) + Expériences sur la liquéfaction de l'oxygéne. (2 papers).‎

‎Paris, Gauthier-Villars, 1877. 4to. No wrappers. In: ""Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences"", Tome 85, No 26 (entire issue offered). With htitle and titlepage to vol. 85. Titlepage with a stamp on verso, seen on front. Pp. 1185-1248. Cailletet's paper: pp. 1213-1214. Pictet's paper: pp. 1214-1217. With an illustration of the apparatus in the text.‎

‎First printing of these two milestone papers in Low-temperature Chemistry. This process of liquefaction of oxygene was achieved independently, in the same year, by Cailletet and Pictet, using different methods. Cailletet used the Joule-Thomson effect"" oxygen was cooled while highly compressed, then allowed to rapidly expand, cooling it further, resulting in the production of small droplets of liquid oxygen. Pictet's method was more elaborate, using compounds pumps. (This compound is shown on the illustration in the text).Parkinson ""Breakthroughs"", 1877 C. - Magee ""Source Books in Physics"" p. 192-93 (Cailletet) and pp. 194-96 (Pictet).‎

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‎"RAOULT, F.-M. (FRANCOIS MARIE). - DISCOVERY OF RAOULT'S LAWS.‎

‎Loi générale de congélation des dissolvants, Mémoire de... (Extrait par l'auteur). (+) Loi générale des tensions de vapeur des dissolvants. (2 Papers).‎

‎(Paris, Gauthier-Villars), 1882. 4to. No wrappers. In: ""Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences"", Tome 95, No 22 a. Tome 104 No 21 (entire issues offered). Pp. 1017-1076 and pp. 1387-1462. Raoult's papers: pp. 1030-33 (tome 95) and pp. 1430-1433 (tome 104).‎

‎First appearance of Raoult's two importent papers in which described a method for finding the molecular weight of an organic compound by the determination of the lowering of the freezing point of water that resulted from dissolving that compound in water and the law governing the relation between solutes and vapor pressure.""Then in 1882, F.-M. Raoult published his results on the effects of nondissociating organic solutes, from which he deduced a general law controlling the lowering of freezing points (the first paper offered). Four years later he extended this work to show the effect of solutes on vapor pressure (the second paper offered). Having established the effect of nondissociating compounds, he was in position to show that salts produced an eeffect which, though anomalous, could nevertheless be explained by the supposition that a dissolved molecule broke up into other molecules. This work was of great value in supplying a new method for determining molecular weights, since the depression of freezing point and vapor pressure (as well a the related rise in boiling point later discovered) are proportional to the moleculat concentrations ofthe solutions"" it was of equal value in supporting the ideas of van't Hoff on osmotic pressure. With the announcement of the dissociation theory of Arrhenius, the anomalies were explained and the full significance of the generalizations of Raoult was recognized. Raoult published the formulations of his laws in the ""Comptes Rendus"" for 1882 and 1887 (the papers offered)"" (Leicester a. Klickstein ""A Source Book in Chemistry"", pp. 471 ff).‎

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‎"DEVILLE, H. SAINTE-CLAIRE - INTRODUCING ""DISSOCIATION"" IN CHEMISTRY.‎

‎De la dissociation ou décomposition spontanée des corps sous l'influence de la chaleur.‎

‎(Paris, Gauthier-Villars), 1857. 4to. No wrappers. In: ""Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences"", Tome 45, No 21. Pp. 833-908 (entire issue offered). Deville's paper: pp. 857-861.‎

‎First printing of Deville's first paper on ""Dissociation"", establishing a new type of high temperature chemistry.""The effect of heat on chemical reactions was of particular interest. From the time of Bergman it had been realized that reactions often followed a course at high temperatures which differed from that followed at lower ones. In 1857, Henri Deville began a eries of studies which established quantitatively a new type of high- temperature reaction... In the course of his studies on the preparation of sodium and potassium and their use as reducing agents in the manufacture of other metals, Deville often used high temperatures. He was aware of the decompositions which often occurred under these conditions, and he suspected that such decompositions were of very frequent occurrence. He therfore undertook the study of reactions which occurred reversibly at high temperature. Such reactions he called 'dissociations', and by an extensive series of studies he showed the importence of dissociation as a general phenomenon in chemistry."" (Leicester a. Klickstein ""A Source Book in Chemistry"", pp. 392 ff.).‎

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‎"WURTZ, ADOLPHE. - ANNOUNCING THE DISCOVERY OF THE AMINES IN CHEMISTRY.‎

‎Sur une série d'alcalis organiques homologues avec l'ammoniaque.‎

‎(Paris, Bachelier), 1849. 4to. No wrappers. In: ""Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences"", Tome 28, No 7. Pp. 189-240 (entire issue offered). Wurtz's paper: pp. 223-226.‎

‎First appearance of the announcement of Wurtz's outstanding discovery of Liebig’s prediction, that there might be organic compounds analogous to ammonia and derivable from it by the replacement of hydrogen - the amines. The entire memoir was not published in full until 1855 in 'Annales de Chimie et de Physique'.Wurtz is most noted for his investigation of glycols and for his discovery of the amines. The latter discovery in 1849 (the paper offered) was very significant at the time, for ot suggested the possibility of a new type, the ammonia type, which helped to explain the behaviour of nitrogenous compounds. (Leicester & Klickstein ""A Source Book.."", pp. 362-63). - Parkinson ""Breakthroughs"" 1849 C.‎

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‎DUMAS, (JEAN BAPTISTE-ANDRE). - THE MAIN PAPER ON SUBSTITUTION AND THE THEORY OF TYPES.‎

‎Mémoire sur la loi des substitutions et la Theorie des types" Séance du Lundi 5 Février 1840.‎

‎Paris, Bachelier, 1840 4to. No wrappers. In: ""Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences"", Tome X , No 5 (entire issue offered). Pp. (143-) 207. Dumas' paper: pp. 149-178.‎

‎First appearance of this paper, which was published the same year in 'Annales de Chimie et de Physique', is the most importent on the theory of structural types and the nomenclature of organic compounds, refuting the electrochemical theory of Berzelius. ""The development of this idea (type organique) into what is sometimes called the ""Older Type Theory"", as distinguished from Gerhardt's Type heory, is contained in Dumas' importent memoir on the substitution and the theory of types, presented on 3 febriary 1840.""(Partington IV, p. 365). ""Jean Baptiste Dumas advances a theory that the chemical properties of an organic compound are determined by its structure and not, as seems to be the case with inorganic compounds, by its electrical properties. he illustrates the concept with the example that the basic qualitative properties of acetic acid are retained even after replacing three fourths of the hydrogen by chlorine. As a consequence, he calls for a revision of chemical nomenclature for organic compounds, basing terms on common features, not on elemental composition.""(Parkinson ""Breakthroughs"" 1840 C).‎

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‎"BERNARD, CLAUDE. - PROOVING THE DOCTRINE OF IRRETABILITY.‎

‎Analyse physiologique des propriètés des systèmes musculaire et nerveux au moyen du curare.‎

‎Paris, Mallet-Bachelier, 1856. 4to. No wrappers. In: ""Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences"", Tome 43, No 18. Pp. (825-) 892. (Entire issue offered). Bernard's paper: pp. 825-829.‎

‎First printin of an importent paper in toxicology in which Bernard describes how he ""paralyzed motor nerve-endings with curare and demonstrated the independent excitability of muscle"" his paper is the classical proof of Haller's doctrine of irretability"" (Garrison & Morton).""Bernard was a true innovator in the study of the effects of toxic and medicinal substances. No one before him had understood so well the role of drug metabolization. He regarded poisoning as a local phenomenon, and advocated the use of certain poisons in physiological research. Curare and carbon monoxide had served him, he said, as ""chemical bistoury,"" making it possible to destroy specific structures selectively. ""(DSB).Garrison & Morton, No 616 and 2079.‎

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‎"PROUST, L.J.‎

‎Sur la Poudre a Canon. 1.-9. Mémoire. (The first memoir with the title: Faits pour servir a L'Étude de la Poudre a Canon).‎

‎Paris, 1811-14. 4to. Contemp. hcalf, richly gilt spine. A paperlabel pasted on lower part of spine. The second leaf with stamps. These 9 papers from ""Journal de Physique, de Chimie et D'Histoire Naturelle"", Tome 70-78, pp. 320-340, pp. 113-126, pp. 266-281, pp.14-36, pp. 376-400, pp. 203-220, pp. 362-392, pp. 334-352 and pp. 169-206. Widemargined, a few scattered brownspots. Some leaves in lower right corner with a wormtract, no loss of letters.‎

‎First printing of these 9 papers by the wellknown French chemist. Proust formulated the ""Law of constant proportion"" which lead to the controversy with Berthollet.‎

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‎"BERZELIUS, JAC.‎

‎Sur la Maniere d'analyser les mines de nickel, et sur une nouvelle combinaison du nickel avec l'arsenic et le soufre.‎

‎(Paris, Crochard, 1818). Without wrappers as extracted from ""Annales de Chimie et de Physique, par Gay-Lussac et Arago"", Tome 9, pp. 113-151(misnumbered as 213-251).‎

‎First printing, the periodical issue.‎

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‎"BERZELIUS, JAC.‎

‎Recherches sur un nouveau corps minéral trouvé dans le soufre fabrique à Fahlun (+) Suite Des Recherches sur un nouveau corps mineral trouvé dans le soufre fabrique à Fahlun (+) Suite Des Recherches...(3 papers). - [THE DISCOVERY OF SELENIUM]‎

‎(Paris, Crochard, 1818). Without wrappers as extracted from ""Annales de Chimie et de Physique. Par Guay-Lussac et Arago"", Tome 9, pp. 160-80, pp. 225--267 and pp. 337-365.‎

‎First printing of these 3 papers which represents Berzelius's discovery of Selenium. Berzelius ""became a partner together with his friends Gahn and Palmstedt in the ownership of a factory near Gripsholm castle, manufacturing sulforic acid, vinegar, soap and white lead.During the summer of 1817 Berzelius spent an entire month supervising the manufacture. This lead to the discovery of a new elemen, Selenium, which he found in the form of a golden-brown sediment in the mud from the bottom of the lead chamber. This was an era when new elements could still be ""scrabed of the walls....what had previously been known as ""Swedish tellurium ore"" was now found to be selenide of copper and silver with a 26 per cent selenium content."" (Jorpes in ""Jac. Berzelius. His Life and Works.p. 61-62)..‎

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‎KRÜSS, GERHARD und HUGO KRÜSS.‎

‎Kolorimetrie und Quantitative Spektralanalyse in ihrer Anwendungen in der Chemie.‎

‎Hamburg u. Leipzig, Leopold Voss, 1891. Contemp. hcalf. Gilt. Spine a bit rubbed. VIII,291,(1) pp., 34 textillustr.and 6 plates.‎

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‎VALLIER, E.‎

‎Balistique des Nouvelles Poudres.‎

‎Paris, Gauthier-Villars, n.d. ca. 1890. Small 8vo. Contemp. hcalf. Spine gilt and with a paperlabel on lower part of spine. Stamps on titlepage. 180 pp.‎

‎(Encyclopedie Scientifique des Aide-Mémoire...publiee de M. Leauté).‎

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‎ANONYMOUS.‎

‎Experiences Sur les Poudres de guerre, faites a Esquerdes, dans les Années 1832, 1833, 1834 et 1835, suivies De Notices sur les Pendules-Balistiques et les Pendules-Canons.‎

‎Paris, J. Corréard, 1837. Uncut in orig. printed wrappers. Stamps on titlepage. (2),92 pp., textillustr. and tables. First and last leaf brownspotted, some brownspots, mainly to margins.‎

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‎"OMODEI, FRANCESCO.‎

‎Dell' Origine della Polvere da Guerra e del primo uso delle Artiglerie a Fuoco. Dissertazione.‎

‎Torino, Stamperia Reale, 1835. 4to. Contemp. hcalf. Spine gilt. Titlelabel with gilt letteringon frontcover. A paperlabel pasted on lower part of spine. Stamp on titlepage. From ""Memoire della Reallle Accademia delle Scienze di Torino"", Tomo XXXVIII, pp. 143-224. Wide margins, clean and printed on good paper.‎

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‎CAZAUX, L.F.G.‎

‎Supplement a L'Essai sur les Effets de la Poudre, ou Recherche des Vitesses initiales dans les Obusiers et les Mortiers.‎

‎Paris, Magimel, Anselin et Pochard, 1818. Uncut in orig. blue blank wrappers. Stamps on titlepage. 42,(1) pp. and 1 folded engraved plate. Scattered brownspots.‎

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‎"MARGGRAF, (ANDREAS SIGISMUND).‎

‎Examen Chymique de L'Eau. (Traduit de Latin).‎

‎(Berlin, Haude et Spener, 1768). 4to. No wrappers, as issued in ""Memoires de L'Academie Royale des Science et Belles Lettres"", tome VII, pp. (131-)157.‎

‎First edition, the periodical form. ""Contemporaries recognized Marggraf as a materful experimental chemist because of the extraordinary range of his interests and the painstaking nature of his procedures.""(DSB).‎

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‎HERZBERG, GERHARD.‎

‎Atomspektren und Atomstruktur. Eine Einführung für Chemiker, Physiker und Physikochemiker. EA! (= Wissenschaftliche Forschungsberichte Naturwissenschaftliche Reihe, hrsg. von R. Ed. Liesegang, Band 37).‎

‎Dresden / Leipzig: Theodor Steinkopff, 1936. Orig. full cloth, cloth on spine loose, slightly soiled. Internally clean. XV, 191 pp. Illustr.‎

Referência livreiro : 41339

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‎"THOMSEN, JULIUS.‎

‎Bidrag til et thermochemisk System [Contributions to a Thermochemical System]. (Særskilt aftrykt af det Kgl. Danske Videnskabernes Selskabs Skrifter, 5te Række, naturvidenskabelig og Matematisk Afdeling, 3die Bind.). - [THE THERMOCHEMICAL AFFINITY PRINCIPLE]‎

‎Kjöbenhavn (Copenhagen), 1852. 4to. Uncut and unopened in the original blue boards (""hollanderet""). A very fine, fresh, and clean copy - near mint, with only a bit of minor sunning to boards. 51 pp.‎

‎First edition, off-print, of the seminal paper that contains the first enunciation of the thermochemical affinity principle and the introduction of the term ""varmetoning"". The present paper represents Thomsen's main work as well as the ""(to use Oswald's words) scientific creed of the chemist for the next half-century. It constituted the only method by which chemists could predict the course of chemical reactions, and Thomsen himself employed the theory in various ways to carry out calculations of this kind."" (Brøndsted in: Meisen edt., Prominent Danish Scientists Through the Ages, p. 143). This breakthrough work, which contains the first statement of a thermochemical nomenclatura and the first definition and presentation of the thermochemical affinity principle, inaugurated a several decades long period of thermochemical studies, during which Thomsen personally carried out more than 3,500 calorimetric measurements in a room kept at 18 degrees celcius. His fundamental thought was that the evolution of heat accompanying a chemical reaction (""varmetoning"") is an exact expression of the chemical affinity of the reaction. Bethelot reached many of the same conclusions a bit later and advanced a theory that in essence was the same as Thomsen's. This led to heated discussions that continued for several years between the two scientists. Thomsen's principle is now usually known as the Thomsen-Berthelot-Principle. In 1883, the Davy Medal was awarded in duplicate, to ""M. Marcellin Berthelot, Member of the Institute of France, and Foreign Member of the Royal Society, and Prof. Julius Thomsen, of Copenhagen"", although Berthelot was obviously preceded by Thomsen. ""The importance of Thomsen's scientific work was rapidly recognized in both Denmark and abroad. In 1860 he was elected member of the Royal Danish Academy of Sciences and Letters. Nine years later he was nominated as professor of physical chemistry at the University of Leipzig, but he refused the offer. Many foreign scientists asked to work under his guidance, but he was afraid that the comparability of the results obtained would be endangered when more than one person performed such measurements and therefore refused all such requests. Thus no school was formed around him. Thomsen was a foreign member of various academies and honorary member of learned societies, and held honorary doctorates from several universities (but not in France, because of the conflict with Berthelot)."" (D.S.B. XIII:359).""Julius Thomsen's international reputation is due largely to his thermochemical studies. He began to work on thermochemical problems in 1850, and in 1852 he published in the ""Videnskabernes Selskabs Skrifter"" a paper entitled ""Bidrag til et thermochemisk System"" [""Contributions to a thermochemical System""], in which he outlined the scheme of his subsequent thorough investigations in this field. This paper contains the first enunciation of the thermochemical affinity principle, which states that chemical affinity, or the attraction between substances, can be measured by the heat evolved when they combine.Ideas as to the nature and laws of chemical affinity were by no means lacking at this period, but the prevalent views were vague, hypothetical and mutually irreconcilable. The great importance of Julius Thomsen's principle when compared with earlier speculations lies not only in its fundamental theoretical ideas, which associate chemical and mechanical phenomena, but also in the fact that the conception of affinity is related to a measurable quantity, the ""Varmetoning"" - a term which Julius Thomsen introduced to include both evolution and absorption of heat - and thus is easily accessible to experimental investigation."" (Brøndsted in: Meisen edt., Prominent Danish Scientists Through the Ages, p. 143).‎

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‎SCHEELE, (CARL WILHELM).‎

‎Berichtigende Bemerkungen über den Luftzünder" von Hrn. Scheele.‎

‎Helmstädt und Leipzig, J.G. Müllerschen Budhhandlung, 1786. Small 8vo. Orig. printed blue wrappers. In: ""Chemische Annalen...von Lorenz Crell"", 1786:1. Bd., 6. Stück. The whole issue (=6. Stück).(4),483-596,(5) pp. Scheele's paper: pp. 483-486.‎

‎First appearance of this paper, by the discoverer of oxygen, which deals with the connection of sulphur and air, showing that ""in thoroughly dry air no pyrophorus takes fire"" moisture must meet with it"", an he notices that metals combine with sulphur in absence of air, with evolution of heat and light. - Parkinson III:p.227.‎

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‎SCHEELE, (CARL WILHELM).‎

‎Neue Beweise der Eigenthümlchkeit der Flussspathsäure" von Hrn. Scheele.‎

‎Helmstädt und Leipzig, J.G. Müllerschen Budhhandlung, 1786. Small 8vo. Orig. printed blue wrappers. In: ""Chemische Annalen...von Lorenz Crell"", 1786:1. Bd., 1. Stück. The whole issue (=1. Stück). (2),96 pp. Scheele's paper: pp. 3-17.‎

‎First appearance of this importent paper, by the discoverer of oxygen, which is the second paper by Scheele which deals with the action of sulphuric acid on fluorspar. (Parkinson III: p.214).‎

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‎SCHEELE, (CARL WILHELM).‎

‎Ueber die wahre Natur des Sauerkleesalzes, und seine künstliche Erzeugung" (+) (Vermischte Chemische Bemerkungen) Brief vom Hrn. Scheele in Köping (an Crell). (2 papers).‎

‎Helmstädt und Leipzig, J.G. Müllerschen Budhhandlung, 1785. Small 8vo. Orig. printed blue wrappers, no backstrip. In: ""Chemische Annalen...von Lorenz Crell"", 17885:1. Bd., 2. Stück. (2),(99-) 192. - Scheele's papers: pp. 112-115 a. pp. 153-155.‎

‎First appearance of 2 papers by the discoverer of oxygen. - The second paper, as a letter to Crell, criticises the view that fixed air is the source off all other acids, a view held by Landriani.- (Partington III:p. 231).‎

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‎SCHEELE, (CARL WILHELM).‎

‎Ueber die Frucht= und Beeren= Säure" vom Hrn. C.W. Scheele.‎

‎Helmstädt und Leipzig, J.G. Müllerschen Budhhandlung, 1785. Small 8vo. Orig. printed blue wrappers, no backstrip. In: ""Chemische Annalen...von Lorenz Crell"", 1785:2. Bd., 10. Stück. (2),(291-)384. - Scheele's papers: pp. 291-303.‎

‎First appearance of a paper by the discoverer of oxygen.‎

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‎"DAVY, HUMPHRY. - INVENTION OF THE ""DAVY-LAMP""‎

‎On the fire-damp of coal mines, and on methods of lighting the mines so as to prevent its explosion. Read November 9, 1815. (And) An account of an invention for giving light in explosive mixtures of fire-damp in coal mines, by consuming the fire-damp....‎

‎(London, W. Bulmer and Co., 1816). 4to. 4to. No wrappers as extracted from ""Philosophical Transactions"" 1816 - Part I. Pp. 1-22 a. pp. 23-24 and 1 large folded engraved plate. showing details of the construction of the lamp. Clean and fine, wide-margined..‎

‎First description and the first announcement of the invention of the Mine Safety Lamp, the so-called ""Davy-Lamp"" together with his further remarks on the functioning of this lamp. The papers are miliestones of applied chemistry.""In 1815 he (Davy) invented the Davy lamp, in which an open flame is surrounded by a cylinder of metallic gauze. Oxygen can get through the gauze and feed the flame. The heat of the flame, however, is dissipated by the metal and explosive gases outside the lamp and not ignited. For the first time, miners were reasonably safe from explosion. In 1818 Davy was made a Baronet for his service to industry."" (Asimow).Dibner: Heralds of Science 181. - Partington IV: p. 36 a. 62-70.‎

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‎"DAVY, HUMPHRY. - A CLASSIC IN ELECTROCHEMISTRY.‎

‎The Bakerian Lecture, On some chemical Agencies of Electricity. Read November 20, 1806.‎

‎(London, W. Bulmer and Co., 1807). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1807 - Part I. Pp. 1-56 and 1 engraved plate. A bit of browning to the plate. Clean and fine, wide-margined..‎

‎First printing of a milestone paper in electrochemistry in which Davy shows that electricity is capable of decomposing the most stable elements.""Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation, but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile, interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle, who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800, and his numerous discoveries were presented in his Bakerian lecture to the Royal Society on November 20, 1806 (the paper offered here). His experiments, along the lines stated in this paper, lead to his discoveries of potassum and sodium in 1807 and the year after to barium, calcium and boron.(A Source Book in Chemistry p. 243). - Sparrow: Milestones of Science No 52. - Wheeler Gift: 2511.‎

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‎DAVY, HUMPHRY - THE DISCOVERY OF POTASSIUM AND SODIUM.‎

‎The Bakerian Lecture, on some new Phenomena of chemical Changes produced by Electricity,particularly the Decomposition of the fixed Alkalies, and the Exhibition of the new substances which constitute their bases" and on the general Nature of alkaline ...‎

‎(London, W. Bulmer and Co., 1808). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1808 - Part I. Pp. 1-44.‎

‎First printing of this importent historical paper in chemistry, in which Davy shows that electricity is capable of decomposing some alkalies, isolating two new substances and discovering potassium and sodium. Neville in his Historical Chemical Library vol. I, p.340, writes about this paper ""ONE OF THE GREAT CLASSIC RESEARCHES IN CHEMISTRY, in which Davy announced in this, his second Bakterian lecture, the isloation of metallic potassium and sodium by the electrolytic decomposition of their fused oxides.""""He (Davy) began his own electrical experiments...The results were spectacular. On October 6, 1807, the current passing through molten potash liberated a metal, which Davy called potassium. The little globules of shining metal tore the water molecule apart as it eagerly recombined with oxygen and the liberated hydrogen burst into lavender flame. Davy danced about in a delirium of joy. A week later he isolated sodium from soda.""(Asimow). The paper offered here describes these discoveries.""Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation, but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile, interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle, who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800, and his numerous discoveries were presented in his Bakerian lecture to the Royal Society on November 20, 1806.(A Source Book in Chemistry p. 243). - Wheeler Gift: 2514.‎

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‎"FARADAY, MICHAEL. - ON ELECTRICAL CONDUCTION OF LIQUIDS.‎

‎Experimental Researches in Electricity. Fourth Series. 9. On a new Law of Electric Conduction. 10. On Conducting Power. (Sections 380-449). Recieved April 24, - Read May 23, 1833.‎

‎(London, Richard Taylor, 1833). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1833 - Part II. Pp. 507-522. and 1 textillustration. Fine and clean.‎

‎First appearance of this importent paper in which Faraday announces his discoveries of the conductability of liquids.""The author, while prosecuting his rechearches on electr-chemical decomposition, oberved some phenomena which, appeared to be referable to a general law of electric conduction not hitherto recognized. He found that an electric current from a voltaic battery, which is readily conducted by water, did not pass through ice: even the thinnest film of iice, interposed in the circuit, was sufficient to intercept all electrical influence of such low intensities as that produced, by the voltaic apparatus, although it allows of the transmission of electricity of such high intensity that ecited by the common electrical machine. The author ascertained that a great number of other substances, which are solid at ordinary temperatures, do not conduct the electric current from the volataic battery until they are liquified."" (Abstract).From 1831 to 1852 Michael Faraday published his ""Experimental Researches in Electricity"" in The Philosophical Transactions of the Royal Society. These papers contain not only an impressive series of experimental discoveries, but also a collection of heterodox theoretical concepts on the nature of these phenomena expressed in terms of lines of forces and fields. He published 30 papers in all under this general title.They represents Faraday's most importent work, are classics in both chemistry and physics and are the experimental foundations for Maxwell's electro-magnetic theory of light, using Faraday's concepts of lines of force or tubes of magnetic and electrical forces. His many experiments on the effects of electricity and magnetism presented in these papers lead to the fundamental discoveries of 'induced electricity' (the Farday current), the electronic state of matter, the identity of electricity from different sources, equivalents in electro-chemical decomposition, electrostatic induction, hydro-electricity, diamagnetism, relation of gravity to electricity, atmospheric magnetism and many other.""Among experimental philosophers Faraday holds by universal consent the foremost place. The memoirs in which his discoveries are enshrined will never ceaseto be read with admiration and delight"" and future generations will preserve with an affection not less enduring the personal records and familiar letters, which recall the memory of his humble and unselfish spirit.""(Edmund Whittaker in 'A History of the Theories of Aether and Electricity' p. 197.‎

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‎"WOLLASTON, WILLIAM HYDE. - CHEMICAL 'EQUIVALENTS' INTRODUCED.‎

‎A Synoptic Scale of Chemical Equivalents. Read November 4, 1813.‎

‎(London, W. Bulmer and Co., 1814). 4to. 4to. No wrappers as extracted from ""Philosophical Transactions"" 1814 - Part I. Pp. 1-22 and 1 engraved plate. Last textleaf slightly browned, otherwise clean and fine.‎

‎First appearance of this importent paper in which Wollaston introduces the ""chemical slide rule"".""In 1814 he draw up ""A Synoptic Table of Chemical Equivalents"", wherein many ""equivalents"" (a term apparently first used in the chemical sense by him) were arranged in a logarithmic scale. Chemists found this device of great practical assistance, and it survives today in the form of the chemical slide rule."" (A Source Book in Chemistry p. 221).""The design of the scale here proposed by the author (Wollaston) is to save chemists the labour of many troublesome computations in estimating the ingredients of neutral salts, and the reagents and precipitates by whic these ingredients might be ascertained."" (Abstract).‎

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‎"HUGGINS, WILLIAM.‎

‎On the Spectra of some of the Chemical Elements. Received November 5, - Read December 10, 1863.‎

‎(London, Taylor and Francis, 1864). 4to. No wrappers as extracted from ""Philosophical Transactions"" Vol. 154 - Part II, pp. 139-160 and 2 large folded engraved plates.‎

‎First appearance of Huggin's series of spectra done with his new spectroscope made of six prism of heavy glass as a preliminary investigation to the work with the spectroscopy of the stars with the star-spectroscope, as it was necessary to have convenient maps of the spectra of terrestrial elements. Huggins devoted a large part of 1863 to the making of 24 such maps with a train of six prismes. These maps were published in the paper offered.""William Huggins (1824-1910), English astronomer, a pioneer in spectroscopy and photography. He examined spectroscopically the chemical constitution of stars and comets, and the gaseous nature of planetary and diffuse nebulae"" he applied the Doppler Principle to the measurement of the radial velocities of stars, and published an atlas of representative stellar spectra"" (Ripley: Source Book in Astronomy).‎

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‎FARADAY, MICHAEL..‎

‎Experimental Researches in Electricity. - Eight Series. 14. On the Electricity of the Voltaic Plate" its source, quantity, intensity, and general Characters. i. On simple Voltaic Circles. ii. On the intensity necessary for Electrolyzation. iii. On a...‎

‎(London, Richard Taylor, 1834). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1834 - Part II. Pp. 425-470 a. 1 engraved plate. Clean and fine.‎

‎First appearance of a historical paper in chemistry and physiscs in which Faraday brings forth the idea ""that the atoms of matter are in some way endowed or associated with electrical powers, to which they owe their most striking qualities, and amongst them their mutual chemical affinity."" He showed how natural it is to suppose that the electricity which passes through the electrolyte is exact equivaklent of that which is possessed by the atoms separated at the electrode: which implies that there is A CERTAIN ABSOLUTE QUANTITY OF THE ELECTRIC POWER ASSOCIATED WITH EACH ATOM OF MATTER.- Faraday further verifies, that the electricity of the violtaic pile is proportionate in its intensity to the intensity of the affinities concerned in its production. - Dealing with the the decompositions in electrolysis, he shows that THE FORCES TERMED CHEMICAL AFFINITY AND ELECTRICITY ARE THE SAME.From 1831 to 1852 Michael Faraday published his ""Experimental Researches in Electricity"" in The Philosophical Transactions of the Royal Society. These papers contain not only an impressive series of experimental discoveries, but also a collection of heterodox theoretical concepts on the nature of these phenomena expressed in terms of lines of forces and fields. He published 30 papers in all under this general title.They represents Faraday's most importent work, are classics in both chemistry and physics and are the experimental foundations for Maxwell's electro-magnetic theory of light, using Faraday's concepts of lines of force or tubes of magnetic and electrical forces. His many experiments on the effects of electricity and magnetism presented in these papers lead to the fundamental discoveries of 'induced electricity' (the Farday current), the electronic state of matter, the identity of electricity from different sources, equivalents in electro-chemical decomposition, electrostatic induction, hydro-electricity, diamagnetism, relation of gravity to electricity, atmospheric magnetism and many other.""Among experimental philosophers Faraday holds by universal consent the foremost place. The memoirs in which his discoveries are enshrined will never ceaseto be read with admiration and delight"" and future generations will preserve with an affection not less enduring the personal records and familiar letters, which recall the memory of his humble and unselfish spirit.""(Edmund Whittaker in A History of the Theories of Aether and Electricity).‎

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‎"FARADAY, MICHAEL.. - SELF-INDUCTION DISCOVERED AND INVESTIGATED.‎

‎Experimental Researches in Electricity. - Ninth Series. . 15. On the Influence of an Electric Current on itself: - and on the inductive action of Electric Currents generally. (Sections 1048-1118). Received December 18, 1834.- Read January 29, 1835.‎

‎(London, Richard Taylor, 1835). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1835 - Part I. Pp. 41-56., 1 textillustr. Clean and fine.‎

‎First appearance of a historical paper in which Faraday (independent of Henry's discovery of the same phenomena in 1832)discovers SELF-INDUCTION or the ""extra current"" and points out the importent influence it must have in the construction of electr-magnetic machines (electro-motors).""Faraday showed that the powerful momentary current, which was observed when the circuit was interrupted, was really an induced current governed by the same laws as all other induced currents, but with this peculiarity, that the induced and inducing current now flowed in the same circuit. In fact, the current in its steady state establishes in the surrounding region a magnetic field, whose lines of force are linked with the circuit"" and teh removal of these lines of forcewhen the circuit is broken originates an induced current, which reatly reinforces the primary current just before its final extinction.""(Whittaker in ""A History of the Aether and Electricity"")""In the series of experiments which are detailed in this paper, the author inquires into the causes of some remarkable phenomena relating to the action of an electrical current upon itself, under certain circumstances, wherby its intensity is highly exalted, and occasionally increased to ten, twenty, or even fifty times that which it originally possessed.""(Abstract).From 1831 to 1852 Michael Faraday published his ""Experimental Researches in Electricity"" in The Philosophical Transactions of the Royal Society. These papers contain not only an impressive series of experimental discoveries, but also a collection of heterodox theoretical concepts on the nature of these phenomena expressed in terms of lines of forces and fields. He published 30 papers in all under this general title.They represents Faraday's most importent work, are classics in both chemistry and physics and are the experimental foundations for Maxwell's electro-magnetic theory of light, using Faraday's concepts of lines of force or tubes of magnetic and electrical forces. His many experiments on the effects of electricity and magnetism presented in these papers lead to the fundamental discoveries of 'induced electricity' (the Farday current), the electronic state of matter, the identity of electricity from different sources, equivalents in electro-chemical decomposition, electrostatic induction, hydro-electricity, diamagnetism, relation of gravity to electricity, atmospheric magnetism and many other.""Among experimental philosophers Faraday holds by universal consent the foremost place. The memoirs in which his discoveries are enshrined will never ceaseto be read with admiration and delight"" and future generations will preserve with an affection not less enduring the personal records and familiar letters, which recall the memory of his humble and unselfish spirit.""(Edmund Whittaker in A History of the Theories of Aether and Electricity).The paper is reprinted in Magie: A Source Book in Physics p.485 ff.‎

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‎"FARADAY, MICHAEL.. - FARADAY'S DOCTRINE OF THE CONSERVATION OF ENERGY.‎

‎Experimental Researches in Electricity. - Sixteenth Series. 24. On the source of power in the voltaic pile. i. Exiting electrolytes, &c. being conductors of thermo and feeble currents. ii. Inactive conducting circles containing an electrolytic fluid...‎

‎(London, Richard and John E. Taylor, 1840). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1840 - Part I. Pp. 61-91 and 1 engraved plate. + Pp. 93-127. Both papers Clean and fine.‎

‎First appearance of a historical paper in chemistry and physiscs in which Faraday announces his principle, that for all known cases of energy, the energy is not generated, but only transformed. The principle he showed applied to the voltaic cell, and he used it to argue against the so-called contact school in chemistry. The process imagined by the contact school ""would indeed be a creation of power, like no other force in nature"". There is no such thing in the world as ""a pure creation of force"" a production of power without a corresponding exhaustion of something to supply it.""""In his very long paper 'on the source of power in the voltaic pile', divided into two parts (XVI and XVII, 1840), faraday marshalled what he thought was owewhelming evidence against the contact theory in favour of the chemical theory.""(Partington: A History of Chemistry IV: p. 138).From 1831 to 1852 Michael Faraday published his ""Experimental Researches in Electricity"" in The Philosophical Transactions of the Royal Society. These papers contain not only an impressive series of experimental discoveries, but also a collection of heterodox theoretical concepts on the nature of these phenomena expressed in terms of lines of forces and fields. He published 30 papers in all under this general title.They represents Faraday's most importent work, are classics in both chemistry and physics and are the experimental foundations for Maxwell's electro-magnetic theory of light, using Faraday's concepts of lines of force or tubes of magnetic and electrical forces. His many experiments on the effects of electricity and magnetism presented in these papers lead to the fundamental discoveries of 'induced electricity' (the Farday current), the electronic state of matter, the identity of electricity from different sources, equivalents in electro-chemical decomposition, electrostatic induction, hydro-electricity, diamagnetism, relation of gravity to electricity, atmospheric magnetism and many other.""Among experimental philosophers Faraday holds by universal consent the foremost place. The memoirs in which his discoveries are enshrined will never cease to be read with admiration and delight"" and future generations will preserve with an affection not less enduring the personal records and familiar letters, which recall the memory of his humble and unselfish spirit.""(Edmund Whittaker in A History of the Theories of Aether and Electricity).‎

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‎"ANDREWS, THOMAS. - THE ""CRITICAL TEMPERATURE"" OF GASES.‎

‎The Bakerian Lecture. - On the Continuity of the Gaseous and Liquid States of Matter. Received June 14, - Read June 17, 1869.‎

‎(London, Taylor and Francis, 1870). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1869 - Vol. 159 - Part II. Pp. 575-590 and 1 plate. Clean and fine.‎

‎First apperance of the paper in which Thomas Andrews announces his discovery of the ""CRITICAL POINT"", which states that for every gas there was a temperature above which pressure alone could not liquefy it.""This was a crucial discovery for it pointed the way toward the liquefaction of the permanent gases by demonstrating the necessity of dropping the temperature below the critical point before exerting pressure. This new view led within half a century to the work of Dewar and Kammerlingh-Onnes and the liquefaction of all known gases.""(Asimov).Magie: A Source Book in Physics, pp. 187-192. - Parkinson, Breakthroughs: 1869 C.‎

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‎"HERSCHEL, JOHN W.F. - INTRODUCING 'POSITIVE' AND 'NEGATIVE' IN PHOTOGRAPHY.‎

‎On the Chemical Action of the Rays of the Solar Spectrum on Preparations of Silver and other Substances, both metallic and non-metallic, and on some Photographic Processes. Received and Read Febrauray 20, 1840. (+) Note I- (III).- On the Distribution ...‎

‎(London, Richard and John E., Taylor, 1840. 4to. No wrappers as extracted from ""Philosophical Transactions"" 1840 - Part I. Pp. 1-59. (Note I- III pp. 51-59) and 2 plates. (one showing Herschel's telescope, lithographed"" the other showing the heat spectrum of the sun in stipple engraving).‎

‎First appearance of an important pioneer-paper in the history of early photography, in which subject John Herschel was one of the main contributors. The paper deals with the dynamical interplay between photochemistry and photography and is of the greatest importence in applied photography. The later sections of the paper deals with the spectrum of the sun, Herschel's so-called thermographical representation of the spectrum of the sun (with description of the Actinograph, invented by him), rendering the heat radiation visible in the spectrum. This first importent spectrum is reproduced here on one of the plates (in stipple engraving). In this paper he introduces the photographical concepts 'positive' and 'negative' to express, respectively, pictures in which the lights and shades are the same as in nature, or as in the original model, and in which they are opposite. For this large paper John Herschel was awarded the Copley archives winners Prize for 1840.""The object which the author has in view in this memoir is to place on record a number of insulated facts and observations respecting the relations bothof white light, and of the differently refrangible rays, to various chemical agents whic have offered themselves to his notice in the course of his photographical experiments, suggested by the announcement of M. Daguerre's discovery.....The terms ""direct"" and ""reverse"" are also used to express pictures in which objects appear, as regards right and left, the same as in the original, and the contrary....The principal objects of inquiry in the present paper...are the following. First, the means of fixing photographs, the comparative merits of different chemical agents...The means of taking photographic copies and transfers.....The preparation of photographic paper....The chemical analysis of the solar spectrum forms the subjects of the next section in the paper...""(Abstract).‎

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‎"FARADAY, MICHAEL.. - ON LIQUEFACTION OF GASES.‎

‎On the Liquefaction and Solidification of Bodies generally existing as Gases. Received December 19, 1844, - Read January 9, 1845. (+) Note.- Additional remarks respecting the Condensation of Gases. Received February 20, - Read February 20, 1845.‎

‎(London, Richard and John E. Taylor, 1845). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1845 - Part I. Pp. 155-177, 1 textillustr. Clean and fine.‎

‎First appearance of an importent paper in chemistry in which Faraday takes up a renewed analysis his great discoveries from 1823 in relation to his liquefaction of gases under pressure and the relation to temperatures. Faraday did pioneer work on liquifaction of gases.‎

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‎"DAVY, HUMPHRY.‎

‎Some experiments and observations on the colours used in painting by the Ancients. Read February 23, 1815.‎

‎(London, W. Bulmer and Co., 1815). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1815 - Part I. Pp. 97-124. Clean and fine.‎

‎First printing of this investigation of the chemical compounds used in Classical times to obtain colours by pigments.He also analysed the colours of the so-called ""Aldobrandini marriage,"" all the reds and yellows of which he discovered to be ochres" the blues and greens, to be oxides of copper the blacks all carbonaceous the browns, mixtures of ochres and black, and some containing oxide of manganese" the whites were all carbonates of lime. ""Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation, but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile, interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle, who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800, and his numerous discoveries were presented in his Bakerian lectures.""‎

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‎DAVY, HUMPHRY. - ISOLATION OF BARIUM, MAGNESIUM, CALCIUM AND STRONTIUM FOR THE FIRST TIME.‎

‎Electro-Chemical Researches, on the Decomposition of the Earth" with Observations on the Metals obtained from the alkaline Earths, and on the Amalgam procured from Ammonia. Read June 30th, 1808.‎

‎(London, W. Bulmer and Co., 1808). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1808 - Part I. Pp. 333-370. Clean and fine.‎

‎First printing of a historical paper in chemistry, his third Bakerian Lecture, in which he obtained for the first time, by means of electrolysis, the metals barium, magnesium, calcium and strontium. He further utilized the strong reducing power of potassium to prepare boron.""Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation, but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile, interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle, who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800, and his numerous discoveries were presented in his Bakerian lectures."" - Not in Wheeler Gift. - The Ronalds Library p. 128.‎

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‎"DANIELL, J. FREDERIC. - THE DANIELL-CELL.‎

‎Further Obervations on Voltaic Combinations. In a Letter addressed to Michael Faraday. Received March 30, - Read April 6, 1837.‎

‎(London, Richard and John E. Taylor, 1837). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1837 - Part I. Pp. 141-160 and 1 engraved plate.‎

‎First appearance of Daniell's second paper on the construction of the famous ""Daniell-Cell"". In 1836 (in a paper in the Transactions, also addressed to Faraday with the title ""On Voltaic Combinations""), he announced his invention of the battery. In his second paper, the paper offered here, he further develops his invention. In the new invention by Charles Wheatstone of the electric telegraph in 1837, the Daniell cell was used as the electric source.In 1831 Daniell was appointed proffesor of Chemistry at King's College London. He invented several scientific instruments, including a hygrometer for measuring humidity he is best known for his work in electrochemistry, his interests having been aroused by the work of his good friend faraday. Volta's battery had the defect of rapid diminution in current. What was needed, however, was a battery yielding a constant current over a considerable lenght of time. In 1836 Daniell succeeded, producing the Daniell cell, of copper and zinc. his was the first reliable source of electric current.‎

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‎"GRAHAM, THOMAS. - CO-FOUNDING PHYSICAL CHEMISTRY.‎

‎Researches on the Arseniates, Phosphates, and Modifications of Phosphoric Acid. Received January 29. Read June 19, 1833.‎

‎(London, Richard Taylor, 1833). 4to. No wrappers as extracted from ""Philosophical Transactions"" 1833 - Part II. Pp. 253-284. Clean and fine.‎

‎First appearance of a main paper in the history of chemistry. ""Graham's major contribution to inorganic chemistry is presented in a paper entitled ""Researcheson thee Arseniates, Phosphates....."" 1833 (the paper offered)...his elucidation of the differences between the three phosphoric acids and his discovery of their polybasicity provided Liebig with the clue to the modern concept of polybasic acids...""(A Source Book in Chemistry p. 333).""In the Preface to...Graham's papers...Dr. Angus Smith has indicated in precise...language Graham's position in that chain of thinkers which includes Leucippus, Lucretius, Newton and Dalton (Thorpe)""Thomas Graham, the Scottish Chemist, first president of the Chemical Society of London, and one of the chief founders of physical chemistry. He formulated Graham's Law of diffusion relating the rate of diffusion of gases to their densities, discovered and named the process of dialysis used for separating colloids from crystalloids, studied the three forms of phosphoric and arsenics acids that led to the developpement of the concept of polybasic acids, a major contribution to inorganic chemistry (the paper offered).‎

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‎"KOPP, HERMANN. - CO-FOUNDING PHYSICAL CHEMISTRY.‎

‎Investigations of the Specific heat of Solid Bodies.‎

‎(London, Taylor & Francis, 1865). Large 4to. Without wrappers. Extracted from ""Philosophical Transactions of the Royal Society of London."", Vol. 155 - Part I. Pp. 71-202 and 1 lithographed plate. Clean and fine.‎

‎First printing. A major paper in physical chemistry, of which he may in some respects be regarded as the founder. Kopp's fame rests mainly, apart from the results presented here on physical chemistry, on his writings dealing with the history of chemistry.""In 1864 Kopp undertook the study of specific heats of a large number of elements and compounds, in an attempt to verify Neumann's law that the product of molecular weight and specific heat is a constant, regardless of the nature of the substance (in the paper offered). He found that in fact the relation was much more complicated and involved a large number of factors. He was, however, able to show that each element has the same specific heat in its free solid state as in its solid compounds. The specific heas of compounds could be calculated from those of their elements"" (DSB).‎

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‎"WOLLASTON, WILLIAM HYDE. - THE DISCOVERY OF THE ELEMENT RHODIUM.‎

‎On a new Metal, found in crude Platina. Read June 24, 1804.‎

‎(London, Bulwer and Co., 1804). 4to. Without wrappers as extracted from ""Philosophical Transactions of the Royal Society of London."" Year 1804-Part II. Pp. 419-430. Clean and fine.‎

‎First appearance of the paper in which Wollaston announced his discovery of the metallic element Rhodium.""Dr. Wollaston dissolved a portion of crude platinum in qgua regia, and neutralized the excess acid with caustic soda. He then added salammoniac to precipitate the platinum as ammonium chloroplatinate, and mercurous cyanide to precipitate the palladium as palladium cyanide. After filteringoff the precipitate, he decomposed the excess mercurous cyanide inthe filtarate by adding hydrochloric acid and evaporating to dryness. When he washed the residue with alcohol, everything dissolved except a beautiful dark red powder, which proved to be a double chloride of sodium and a new metal, which because of the rose color of its salts, Dr. Wollaston named 'Rhodium'. He found that the sodium rhodium chloride could be easely reduced by heating it in a current of hydrogen, and that after the sodium chloride had been washed out, the rhodium remained as a metallic powder. he also succeeded in obtaining a rhodium button.""(Weeks: Discovery of the Elements. p. 104-05.)‎

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