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BROGLIE (DEBROGLIE), LOUIS de - DISCOVERY OF THE WAVE THEORY OF MATTER AND CREATION OF WAVE-MECHANICSBiblio.com

Ondes et quanta. Note de M. Louis de Broglie présentée par M. Jean Perrin. Séance du 10 Septembre 1923. Quanta de lumière diffraction et interférences. Note de M. Louis de Broglie transmise par M. Jean Perrin. Séance du 24 Septembre 1923. .

1923Best.-Nr. 46949Paris Gauthier-Villars et Cie 1923. 4to. Bound in 2 contemp. full cloth. Spines gilt and with gilt lettering. In: "Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences" Tome 177. With htitle a. titlepage. 1513 pp. Entire volume offered. De Broglie's papers: pp. 507-510 pp. 548-551 a. pp. 630-32. Clean and fine. A stamp to verso of titlepage. First edition of these papers which ESTABLISHED A NEW ERA IN PHYSICS by introducing the epochal new principle that particle-wave duality should apply not only to radiation but also to matter and thus CREATING QUANTUM MECHANICS. These 3 papers were extended to form his doctoral thesis of 1924 "Recherches sur la Théorie des Quanta."De Broglie relates "After long reflection in solitude and meditation I suddenly had the idea during the year 1923 that the discovery made by Einstein in 1905 should be generalized by extending it to all material particles and notably to electrons" Preface to his PhD thesis 1924."He made the leap in his September 10 1923 paper: E=hv should hold not only for photons but also for electrons to which he assigns a 'fictitious associated wave'. In his September 24 paper he indicated the direction in which one 'should seek experimental confirmations of our ideas': a stream of electrons traversing an aperture whose dimensions are small compared with the wavelenght of the electron waves 'should show diffraction phenomena' ."Pais "Subtle is the Lord" pp. 425-436.In the third paper October 8 he discusses "The interplay between the propagation of the particle and of the waves could be expressed in more formal terms as an identity between the fundamental variational principles of Pierre de Fermat rays and Pierre Louis Maupertuis particles as de Broglie discussed it further in his last communication . Therein he also considered some thermodynamic consequences of his generalized wave-particle duality. He showed in particular how one could using Lord Rayleigh’s 1900 formula for the number of stationary modes for phase waves obtain Planck’s division of the mechanical phase space into quantum cells.Louis de Broglie achieved a worldwide reputation for his discovery of the wave theory of matter for which he received the Nobel Prize for physics in 1929. His work was extended into a full-fledged wave mechanics by Erwin Schrödinger and thus contributed to the creation of quantum mechanics. After an early attempt to propose a deterministic interpretation of his theory de Broglie joined the Copenhagen school’s mainstream noncausal interpretation of the quantum theory."DSB."This idea i.e. de Broglie's that matter might behave as waves was tested and confirmed by Davisson and Germer in 1927. Thus the duality of both light and matter had been established and physicists had to come to terms with fundamental particles which defied simple theories and demanded two sets of 'complementary' descriptions each applicable under certain circumstances but incompatible with one another." Printing and the Mind of Man 417. hardcover

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LEIBNIZ (LEIBNITZ), GF - CHRISTIAAN HUYGENS - JOHANN BERNOULLI - JACOB BERNOULLI ET AL - THE DISCOVERY OF THE "CATENARY CURVE"Biblio.com

1. De Linea in quam Flexile se pondere proprio curvat ejeuque usu insignia adinveniendi quotcunque medias proportionales & Logarithmos. - 2. De Solutionibus Problematis Catenarii vel Funicularis in Actis A. 1691 aliisque a Dn. I.B. propositis. 1-2:.

1691Best.-Nr. 41859Leipzig Grosse & Gleditsch 1691. 4to. Contemp. full vellum. Faint handwritten title on spine. a small stamp on titlepage. In: "Acta Eruditorum Anno MDCLXXXXI". 85906 pp. and 13 of 15 folded engraved plates. The 2 first plates lacks but they do not belong to the papers listed.Leibniz' papers: pp.277-281 a. 1 plate pp. 435-439. Johann Bernoulli: pp. 274-276 a. 1 plate. Huygens: pp. 281-282. - Jacob Bernoulli: pp. 282-290 a. 1 plate. All papers first apperance. All 5 of extreme importence in the development of the Calculus. Leibniz' 2 papers on the catenary curve paper 1-2 offered here was written at the instigation of Jacques Bernoulli. Following the example of Blaise Pascal who had initiated in 1658 a contest for the construction of the cycloid Leibniz also provoked the geometers of his time by challenging them to submit at the fixed date of mid-1691 their geometric method for the construction of the catenary curve. Leibniz later provided the answer followed by Johann Bernoulli and Huygens.'These two papers are a historical account of the origin of the study of this transcendental curve and at the same time the first physical-geometric construction showing the species-relationship between the catenary and the logarithmic curves as two companion curves; one arithmetic the other geometric. All of the differentials of the catenary curve are arithmetic means of corresponding differentials of the logarithmic curve; and all of the differentials of the logarithmic curve are geometric means of the catenary.'"The Catenary is the form of a hanging fully flexible rope or chain the name comes from "catena" which means 'chain' suspended on two points. The interest in this curve originated with Galileo who thought that is was a parabola. Young Christiaan Huygens proved in 1646 that this cannot be the case. What the actual form was remained an open question till 1691 when Leibniz Johann Bernoulli and the then much older Huygens sent solutions to the problem to the "Acta" Jakob Bernoulli 1690 Johann Bernoulli 1691 Huygens 1691 and Leibniz 1691 - these 4 1691-papers offered here - in which the previous year Jakob Bernoulli had challenged mathematicians to solve it. As published the solutions did not reveal the methods but through later publications of manuscripts these methods have been known. Huygens applied with great paper 4 virtuosity the by then classical methods of 17th century infinitesimal mathematics and he needed all his ingenuity to reach a satisfactory solution. Leibniz the papers 1-2 and Bernoulli paper 3 applying the new Calculus found the solutions in a much direct way. In fact the catenary was a test-case between the old and the new style in the study of curves and only because the champion of the old style was a giant like Huygens the test-case can formally be considered as ending in a draw." Grattan-Guiness in "From the Calculus to Set Theory 1630-1910.".The paper by JACOB BERNOULLI no. 5 offered here is a milestone papers as it marks the invention of the "SYSTEM OF POLAR COORDINATES" with points located by reference to a fixed point and a line through that point. Although newton had earlier also devised such a coordinate system in 1671 his work was not known so that the credit for the discovery generally goes to Bernoulli. Parkinson Breakthroughs 1691.Further papers contained in this volume of Acta Eruditorum:DENYS PAPIN: Mecanicorum de Viribus Motricibus sententia asserta a D. Papino adversius C.G.G. L. Leibniz objectiones. pp. 6-13. The plate lacks. - and Dion. Papini Observationes quaedam circa materias ad Hydraulicam spectantes. Pp. 208-213 a. 1 plate. This importent paper is part of the LEIBNIZ-PAPIN-CONTROVERSY.JACOB BERNOULLI: Specimen Calculi Differentialis in dimensione Parabolæ helicoidis ubi de flexuris curvarum in genere carundem evolutionibus. Pp. 13-22. The plate lacks. - and J.B. Demonstratio Centri Oscillationis ex Natura Vectis reperta occassione eorum quæ super hac materia in Historia Literaria Roterodamensi recensentur articulo.Pp.317-321.LEIBNIZ: O.V.E. Additio ad Schediasma de Medii Resistentia publicatum in Actis mensis Febr. 1889. Pp. 177-178. and O.V.E. Quadratura Arithmetica Communis Sectionum Conicarum quæ centrum babent.Pp. 178-182 a. 1 plate.TSCHIRNHAUS: Singularia Effecta Vitri Caustici bipedalis quod omnia magno sumtu hactenus constructa specula ustoria virtute superat per D.T. Pp. 517-520 hardcover

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CURIE, JACQUES et PIERRE - THE DISCOVERY OF PIEZOELECTRICITYBiblio.com

Développement par pression de l'èlectricité polaire dans les cristaux hémièdres à faces inclinées. Note de MM. Jacques et Pierre Curie présentée par M. Friedel.

1880Best.-Nr. 47008Paris Gauthier-Villars 1880. 4to. No wrappers. In: "Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences" Tome 91 No 5 entire issue offered. Pp. 251-310. The Curie's paper: pp. 294-295. First apperance of the paper in which the two brothers announced their discovery of the Piezoelectric Effect as they observed how an electric potential appeared across crystals of quartza and of Rochelle salt when pressure was applied to them. The potential varied directly with the pressure and they named the phenomenon Piezoelectricity meaning "to press" Greek. Crystals with piezoelectric properties form an essential portion of sound-electronics devices such as microphones and record-players."The applications of piezoelectric crystals are innumerable; one of the most important is their use in frequency stabilization of oscillating electromagnetic cirasciots for radio broadcasting stations. They are used in most piezometers for measuring with great precision either very strong pressure variations such as those of a cannon at the moment of firing or very weak ones such as artery pulsations. These applications have led to the creation of a new industry the manufacture of large "mono" such as quartz obtained hydrothermally around 500°C. under high water pressures or crystals such as Rochelle salt obtained from aqueous solutions. These two substances were mentioned in the Curie brothers’ report announcing the discovery of piezoelectricity." DSB."The first experimental demonstration of a connection between macroscopic piezoelectric phenomena and crystallographic structure was published in 1880 by Pierre and Jacques Curie. Their experiment consisted of a conclusive measurement of surface charges appearing on specially prepared crystals tourmaline quartz topaz cane sugar and Rochelle salt among them which were subjected to mechanical stress. These results were a credit to the Curies' imagination and perseverance considering that they were obtained with nothing more than tinfoil glue wire magnets and a jeweler's saw." Piezo Systems Inc.Magee "A Source Book in Physics" p. 547 ff. unknown

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RAOULT, F-M (FRANCOIS MARIE). - DISCOVERY OF RAOULT'S LAWSBiblio.com

Loi générale de congélation des dissolvants Mémoire de. Extrait par l'auteur. Loi générale des tensions de vapeur des dissolvants. 2 Papers.

1882Best.-Nr. 47024Paris Gauthier-Villars 1882. 4to. No wrappers. In: "Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences" Tome 95 No 22 a. Tome 104 No 21 entire issues offered. Pp. 1017-1076 and pp. 1387-1462. Raoult's papers: pp. 1030-33 tome 95 and pp. 1430-1433 tome 104. First appearance of Raoult's two importent papers in which described a method for finding the molecular weight of an organic compound by the determination of the lowering of the freezing point of water that resulted from dissolving that compound in water and the law governing the relation between solutes and vapor pressure."Then in 1882 F.-M. Raoult published his results on the effects of nondissociating organic solutes from which he deduced a general law controlling the lowering of freezing points the first paper offered. Four years later he extended this work to show the effect of solutes on vapor pressure the second paper offered. Having established the effect of nondissociating compounds he was in position to show that salts produced an eeffect which though anomalous could nevertheless be explained by the supposition that a dissolved molecule broke up into other molecules. This work was of great value in supplying a new method for determining molecular weights since the depression of freezing point and vapor pressure as well a the related rise in boiling point later discovered are proportional to the moleculat concentrations ofthe solutions; it was of equal value in supporting the ideas of van't Hoff on osmotic pressure. With the announcement of the dissociation theory of Arrhenius the anomalies were explained and the full significance of the generalizations of Raoult was recognized. Raoult published the formulations of his laws in the "Comptes Rendus" for 1882 and 1887 the papers offered" Leicester a. Klickstein "A Source Book in Chemistry" pp. 471 ff. unknown

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BERNARD, CLAUDE - THE DISCOVERY AND ISOLATION OF GLYCOGENEBiblio.com

Sur le mécanisme de la formation du sucre dans le foie. Suite Sur le mécanisme. Remarques sur la formation de la matière glycogène du foie. 3 Papers.

1855Best.-Nr. 47110Paris Mallet-Bachelier 1855 a. 1857. 4to. No wrappers. In: "Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences" Tome 41 No 13 and Tome 44 No 12 a. No. 26. Pp. 461-500 pp. 578-640 a. pp. 1293-1363 3 entire issues offered. Bernard's papers: pp. 461-469 pp. 578-586 a. pp. 1325-1331. Some scattered brownspots to the first paper. First printing of these two milestone-papers in physiology in which Bernard discovers and isolates glycogen from the liver shows that it is converted into blood glucose and discovers the process of gluconeogenesis. He further creates the concepts "experimental determination" and "local interieur"Bernard undertook the task of tracing out the various transformations of food stuffs within the animal organism beginning with the carbohydrates; and he not only found contrary to the accepted view that sugar was formed in the liver but he was also able to isolate a substance from the hepatic tissue which though not sugar was converted by fermentation into dextrose. He made a special study of its properties and called it "glycogen"."The culmination of Bernard's work on the glycogenic function of the liver. He invented the term "internal secretion" and can be said to have started the scientific investigation of the internal secretions although for 30 years the significance of his work was not generally realized. By his research on glycogene Bernard showed that the body not only can break down but can also build up complex chemical substances."Garrison & Morton .Claude Bernard 1813-78 was a key figure in French nineteenth-century science and one of the world's great physiologists. With good reason he has been called the ‘father of experimental medicine’.Garrison & Morton No. 1000 a. 999.1 unknown

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DAVY, HUMPHRY - THE DISCOVERY OF POTASSIUM AND SODIUM (FRENCH VERSION).Biblio.com

Recherches ëlectrochimiques sur la décomposition des terres avec des observations sur les métaux obtenus des terres alcalines et sur un amalgame produit avec l'ammoniaque. Tireeis des Transactions philosophiques et traduites par M. C.A. Prieur. .

1809Best.-Nr. 50198Paris Mad. Ve Barnard 1809. Contemp. hcalf. Spine gilt. Wear to top of spine. A few scratches to binding. Small stamps on verso of titlepage.In: "Annales de Chimie ou Recueil de Mémoires concernant la Chemie" Tome 70. 336 pp. Entire volume offered. Davy's paper: pp. 189-254. First edition in French the first English 1808 of this importent historical paper in chemistry in which Davy shows that electricity is capable of decomposing some alkalies isolating two new substances and discovering potassium and sodium. Neville in his Historical Chemical Library vol. I p.340 writes about this paper "ONE OF THE GREAT CLASSIC RESEARCHES IN CHEMISTRY in which Davy announced in this his second Bakterian lecture the isloation of metallic potassium and sodium by the electrolytic decomposition of their fused oxides.""He Davy began his own electrical experiments.The results were spectacular. On October 6 1807 the current passing through molten potash liberated a metal which Davy called potassium. The little globules of shining metal tore the water molecule apart as it eagerly recombined with oxygen and the liberated hydrogen burst into lavender flame. Davy danced about in a delirium of joy. A week later he isolated sodium from soda."Asimow. The paper offered here describes these discoveries."Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800 and his numerous discoveries were presented in his Bakerian lecture to the Royal Society on November 20 1806. A Source Book in Chemistry p. 243. unknown

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RITTER, (JOHANN W). - THE DISCOVERY OF "CHEMICAL RAYS" - ULTRAVIOLET LIGHT AND RADIATIONBiblio.com

Announcing his discovery of ultraviolet light "Von den Herren Ritter und Bückmann. - - Am 22sten Febr. habe ich auch auf der Seite des Violetts im Farbespectrum ausserhalb desselben Sonnenstrahlen angetroffen.

1801Best.-Nr. 43492Halle Rengerschen Buchhandlung 1801. Without wrappers as published in "Annalen der Physik. Herausgegeben von Ludwig Wilhelm Gilbert" Bd. 7 Viertes Stück. The entire issue offered =Heft 4. Pp. 387-528. Ritter's announcement p. 525. With titlepage to volume 7. Clean and fine. Titlepage a bit shavedin inner margin. First printing of Ritter's announcement of his discovery of ultraviolet light in a halfpage letter addressed to Gilbert's Annalen. With that discovery it became clear that visible light represents no more than a fraction of a continous spectrum.A year earlier in 1800 William Herschel discovered infrared light. This was the first time that a form of light beyond visible light had been detected. After hearing about Herschel's discovery of an invisible form of light beyond the red portion of the spectrum Ritter decided to conduct experiments to determine if invisible light existed beyond the violet end of the spectrum as well. He had heard that blue light caused a greater reaction in silver chloride than red light did. Ritter decided to measure the rate at which silver chloride reacted to the different colors of light. He directed sunlight through a glass prism to create a spectrum. He then placed silver chloride in each color of the spectrum and found that it showed little change in the red part of the spectrum but darkened toward the violet end of the spectrum. Johann Ritter then decided to place silver chloride in the area just beyond the violet end of the spectrum in a region where no sunlight was visible. To his amazement this region showed the most intense reaction of all. This showed for the first time that an invisible form of light existed beyond the violet end of the visible spectrum. This new type of light which Ritter called Chemical Rays later became known as ultraviolet light or ultraviolet radiation the word ultra means beyond. - Parkinson Breakthroughs: 1801 P. unknown

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FARADAY, MICHAEL - THE DISCOVERY OF ELECTRO-MAGNETIC INDUCTION (PMM 308) - FRENCH VERSIONBiblio.com

Recherches expérimentales sur l'Electricité. § I-V. I. Sur l'induction des courans l'èlectriques. II. Sur le développement de l'électricité par le magnetisme. III. Sur une nouvelle condition électrique de la matière. IV. Sur les phénomènes magnét.

1832Best.-Nr. 44145Paris Crochard 1832. Contemp. hcalf. gilt spine light wear along edges. In: "Annales de Chimie et de Physique Par MM. Gay-Lussac et Arago." tome 50 Series 2. Entire volume offered. 448 pp. 2 folded engraved plates. Faraday's papers: pp. 5-67 a. pp. 113-162. First French editions of the 2 first memoirs of Faradays groundbreaking researches on electricity constituting the first 2 papers of his "Experimental Researches in Electricity" and containing his fundamental discovery of electromagnetic induction THE FOUNDATION OF NEARLY ALL THE ELECTRICITY IN USE TODAY. In 1820 Oersted had generated magnetism from electricity Faraday here finds the opposite effect generating electricity by magnetism. He also described the first electrical generator second paper. THESE PAPERS ARE SOME OF THE GREAT CLASSICS OF CHEMISTRY AND PHYSICS."Faraday demonstrated this theory involving the lines of force.by inserting a magnet into a coil of wire attached to a galvanometer. While the magnet was being inserted or removd current flowed through the wire. If the magnet was held stationary and the coil moved over it one way or the other there was current in the wire. In either case the magnetic lines of force about the magnet were cut by the wire.If the magnet and coil were both held motionless whether the magnet was within the coil or not there was no current.Faraday hd thus discovered electricalinduction.It was to lead to great things but this was not apparent."Asimov."Although his discovery of the electric motor and the dynamo was almost entirely identical to his theoretical discoveries it laid the foundation of the modern electrical industry - electric light and power teælephony wireless telegraphy televison etc. - by providing for the production of continous mechanical motion from an electrical source and vice versa." PMM 308.Horblit 29 - Milestones 62. - Dibner 64. - PMM 308. unknown

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DAVY, HUMPHRY - THE DISCOVERY OF THE ANAESTETHIC EFFECTS OF "LAUGHING GAS"Biblio.com

Athembarkeit des sauerstoffhaltigen Stickgas; aus einem Briefe H.Davy's an Will. Nicholson. Nachricht von einigen merkwürdigen Versuchen Davy's. Aus einem Briefe Humphry Davy's an Will. Nicholson.

1799Best.-Nr. 44095Halle Rengerschen Buchhandlung 1799 1800. Without wrappers extracted from "Annalen der Physik. Herausgegeben von Ludwig Wilhelm Gilbert" Bd. 2. p. 483 one page. and Bd. 6 pp. 105-115. Some scattered brownspots. First German translation of Davy's announcement the announcement on 1 page of his discovery of the unusual anaesthetic effects of nitrous oxide which on being inhaled gave rise to a giddy intoxicated feeling. On announcing his discovery he says that he will publish a paper discribing the experiments with the gas later. This is the paper offered here also in the first German version. Both the announcement and the paper were issued in the "Annalen" the same year as they appeared in Nicholson's Journal.The gas was first synthesized by English natural philosopher and chemist Joseph Priestley in 1772 who called it phlogisticated nitrous air."Following Priestley's discovery Humphry Davy of the Pneumatic Institute in Bristol England experimented with the physiological properties of the gas such as its effects upon respiration. He even administered the gas to visitors to the institute and after watching the amusing effects on people who inhaled it coined the term 'laughing gas'! Davy even noted the anaesthetic effects of the gas: "As nitrous oxide in its extensive operation appears capable of destroying physical pain it may probably be used with advantage during surgical operations in which no great effusion of blood takes place".Wikipedia."Davy discovered the anaesthetic properties of nitrous oxide and suggested its use during surgiical operations a suggestion which was not turned to useful account until 1844."Garrison & Morton 5646 not mentioning the announcing of its discovery in 1799. unknown

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PASTEUR, LOUIS - ANNOUNCING THE DISCOVERY OF "MOLECULAR ASSYMETRY"Biblio.com

Mémoire sur la relation qui peut exister entre la forme cristalline et la composition chimique et sur la cause de la polarisation rotatoire; Extrait. Séance du Lundi 22 Mai 1848.

1848Best.-Nr. 49456Paris Bachelier 1848. 4to. No wrappers. In: "Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences" Tome 26 No 21. Pp. 529- 548. Entire issue offered. Pasteur's paper: pp. 535-538. Clean and fine. First appearance of the announcement of Pasteur's momentous and revolutionary discovery of "molecular assymetry" and founding the science of Polarimetry.The discovery was first announced by Pasteur in may 1848 by the printing of the preliminary report of only 4 short pages in order to establish priority the paper offered. A more full exposition was published the same year in "Annales de Chimie et de Physique" 3me Series - Tome XXIV."In 1848.Pasteur studied the crystals of tartrates one of the substances that exhibited the now-clockwise now-counterclockwise effect under the microscope and found that the xcrystasls were mirror images of the others. The two crystals resemmbled each other as a right-hand glove resembles a left-hand glove.This was a revolutionary discovery and it took some courage to announce it. A few years before the well-known chemist Mitscherlich had studies the same tartrate crystals and declared them all to be identical. Pasteur was only a twenty-sic-year-old unknown. neverthelless he announced his findings and went before Biot to repeat the separation ofthe crystals before the eyes of the aged authority in the field. Biot was convinced and Pasteur received the Rumford medal of the Royal Society for his work.Pasteur had thus founded the science of polarimetry in which the measurements of the manner in which the plane of polarized light was twisted could be used to help to determine the structure of organic substance to follow various chemical reactions and so on."Asimov. Leicester & Klickstein "A Source Book of Chemistry" p. 374-379. unknown

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