Discovery

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PASTEUR, LOUIS - ANNOUNCING THE DISCOVERY OF "MOLECULAR ASSYMETRY"Biblio.com

Mémoire sur la relation qui peut exister entre la forme cristalline et la composition chimique et sur la cause de la polarisation rotatoire; Extrait. Séance du Lundi 22 Mai 1848.

1848ref. 47149Paris Bachelier 1848. 4to. No wrappers. In: "Comptes Rendus Hebdomadaires des Séances de L'Academie des Sciences" Tome 26 No 21. Pp. 529- 548. Entire issue offered. Pasteur's paper: pp. 535-538. First appearance of the announcement of Pasteur's momentous and revolutionary discovery of "molecular assymetry" and founding the science of Polarimetry.The discovery was first announced by Pasteur in may 1848 by the printing of the preliminary report of only 4 short pages in order to establish priority the paper offered. A more full exposition was published the same year in "Annales de Chimie et de Physique" 3me Series - Tome XXIV."In 1848.Pasteur studied the crystals of tartrates one of the substances that exhibited the now-clockwise now-counterclockwise effect under the microscope and found that the xcrystasls were mirror images of the others. The two crystals resemmbled each other as a right-hand glove resembles a left-hand glove.This was a revolutionary discovery and it took some courage to announce it. A few years before the well-known chemist Mitscherlich had studies the same tartrate crystals and declared them all to be identical. Pasteur was only a twenty-sic-year-old unknown. neverthelless he announced his findings and went before Biot to repeat the separation ofthe crystals before the eyes of the aged authority in the field. Biot was convinced and Pasteur received the Rumford medal of the Royal Society for his work.Pasteur had thus founded the science of polarimetry in which the measurements of the manner in which the plane of polarized light was twisted could be used to help to determine the structure of organic substance to follow various chemical reactions and so on."Asimov. Leicester & Klickstein "A Source Book of Chemistry" p. 374-379. unknown

Herman H. J. Lynge & Søn A/S · DenmarkDKK 4,500.00≈ €602.02

RAYLEIGH, LORD (JW STRUTT) and WILLIAM RAMSAY - THE DISCOVERY OF ARGON J WBiblio.com

Argon a New Constituent of the Atmosphere. Received and Read January 31 1895.

1895ref. 42221London Harrison and Sons 1895. 4to. No wrappers as extracted from "Philosophical Transactions" Vol. 186 - I Series A. Pp. 187-241 a. 8 textillustrations apparatus. Fine and clean. First printing of this importent paper in the history of chemistry Lord Rayleigh's most famous discovery announcing the discovery of this new gas the first finding of one of the rare gases inert gases having unusual properties and forming a distinct group in the periodic table and all with zero valency."The original paper in the "Philosophical Transactions" will undoubtly rank as a classic the investigation having been a particularly brilliant ine." Ernst von Meyer in History of Chemistry. For this discovery Lord Rayleigh and W. Ramsay received the Nobel Prize 1904.After having made several measuring of the densities of gases "Rayleigh came across a curious puzzle. With oxygen he always obtained the same density regardless of how the oxygen might be produced whether from one particular compound from a second compound or from the air. The situation was different with nitrogen. The nitrogen he obtained from air constantly showed a slightly higher density than the nitrogen he obtained from any of various compounds. Rayleigh could think of several ways in which the nitrogen obtained from air might be contaminated but none of the possibilities checked out experimentally. He was so frustrated that he went so far as to write to the journal "Nature" asking for suggestions. Ramsay a brilliant Scottish chemist asked permission to tackle the problem and received it. The upshot was that a new gas somewhat denser that nitrogen was discovered to exist in the atmosphere. It was named argon and it was the first of a series of rare gases of unusual properties whose existence had never been suspected."Asimow.Dibner Heralds of Science No. 50 - Neville Historical Chemical Library vol. II p.358. unknown

Herman H. J. Lynge & Søn A/S · DenmarkDKK 5,500.00≈ €735.81

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